11-[3-Methoxycarbonyl-5-[10-[(2-methylpropan-2-yl)oxycarbonylamino]decoxy]phenoxy]undecanoic acid | 444753-41-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 11-[3-Methoxycarbonyl-5-[10-[(2-methylpropan-2-yl)oxycarbonylamino]decoxy]phenoxy]undecanoic acid
• CAS: 444753-41-7
• 化学式: C₃₄H₅₇NO₈
• 分子量: 607.828
• InChiKey: JWBZNGBGHIZKQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  43
• 可旋转键数：
  28
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  120
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  11-[3-Methoxycarbonyl-5-[10-[(2-methylpropan-2-yl)oxycarbonylamino]decoxy]phenoxy]undecanoic acid 在 N-甲基吡咯烷酮 、 盐酸 、 1-羟基苯并三唑 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 乙酸乙酯 为溶剂， 生成
  参考文献：
  名称：

  New bisamides gelators: relationship between chemical structure and fiber morphology

  摘要：

  Different dialkoxybenzoic acid derivatives with identical alkyl chain lengths were synthesized and their properties as organogelators evaluated. Only the compounds bearing amide groups behave like gelators. Their gelation abilities and phase diagrams were described. A structural study was conducted by freeze-fracture electron microscopy and showed that the methyl ester formed platelet-like aggregates whereas the corresponding free acid formed thin fibers in the gel. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00456-8
• 作为产物：
  描述：

  N-(tertbutyloxycarbonyl)-10-aminodecyl methanesulfonate 在 palladium on activated charcoal 四丁基溴化铵 、 氢气 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 25.0 ℃ 、133.32 Pa 条件下， 反应 4.0h， 生成 11-[3-Methoxycarbonyl-5-[10-[(2-methylpropan-2-yl)oxycarbonylamino]decoxy]phenoxy]undecanoic acid
  参考文献：
  名称：

  Toward folding control in oligomers and polymers

  摘要：

  A facile synthetic route affording polycondensable monomers containing alkyl chains connected to a rigid aromatic core allowing chain folding was developed. The stepwise condensation of the monomer was shown to afford dimer, tetramer and was further proved to be applicable to higher oligomers. Such oligomers composed of "tinker toy" building blocks may be of interest for inducing controlled conformations in nanostructured materials. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00063-5