{4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyanine}(acetato)luthetium(III) | 168292-95-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: {4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyanine}(acetato)luthetium(III)
• CAS: 168292-95-3
• 化学式: C₆₆H₇₅LuN₈O₂₂
• 分子量: 1507.33
• InChiKey: BRCDIZQVCCDVIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  4,5-bis(1,4,7,10-tetraoxaundecyl)phthalonitrile 、 {4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyanine}(acetato)luthetium(III) 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 further solvent(s) 为溶剂， 以7.5%的产率得到2,(3),9(10),16(17),23(24)-(tetraphenoxyphthalocyaninato)lutetium(III) acetate
  参考文献：
  名称：

  Ionoelectronics. Cation-Induced Nonlinear Complexation: Crown Ether- and Poly(ethylene oxide)-Substituted Lutetium Bisphthalocyanines

  摘要：

  Lutetium bisphthalocyanines symmetrically substituted with crown ether macrocycles ([(15-C-5)(4)Pc]Lu-2, [(18-C-6)(4)Pc]Lu-2) or linear poly(ethylene oxide) chains ([(RO)(8)Pc]Lu-2) have been synthesized and characterized. An unsymmetrical complex ([(15-C-5)(4)Pc]Lu[Pc(OR)(8)]) is also described. The selectivity of complexation toward alkali cations is determined by the picrate extraction method. Titration curves have been obtained by UV-visible spectroscopy, showing that large alkali cations induce the formation of aggregates via a positive cooperativity effect. A sigmoidal titration curve is obtained for the couple [(18-C-6)(4)Pc]Lu-2/Rb+. The shape of the curve is very similar to the one obtained for the complexation of O-2 by hemoglobin, where a nonlinear binding process is well established. The obtainment of this phenomenon is a key step toward the realization of ionoelectronics networks.

  DOI：

  10.1021/ja00091a046

文献信息

• Ionoelectronics: synthesis and surface grafting of an unsymmetrical lutetium bisphthalocyanine bearing four crown-ether moieties and four hexanoic acid side chains
  作者：Felix Steybe、Jacques Simon

  DOI：10.1039/a807376g

  日期：——

  The synthesis of an unsymmetrical lutetium bisphthalocyanine for ionoelectronics is reported.

  报告了一种用于离子电子学的非对称镥双酞菁的合成。
• Lapkina; Larchenko; Tolkacheva, Russian Journal of Inorganic Chemistry, 1998, vol. 43, # 6, p. 901 - 909
  作者：Lapkina、Larchenko、Tolkacheva、Popov、Konstantinov、Nosova、Tzivadze

  DOI：——

  日期：——