[Pd(dmit)(Me2pipdt)] | 1211997-23-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: [Pd(dmit)(Me2pipdt)]
• 英文别名: [Pd(1,3-dithiolo-2-thione-4,5-dithiolato)2(1,4-dimethyl-piperazine-3,2-dithione)]
• CAS: 1211997-23-7
• 化学式: C₉H₁₀N₂PdS₇
• 分子量: 477.074
• InChiKey: AYLWOLPHUYCXRZ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  (n-Bu₄N)₂[Ni(2-thioxo-1,3-dithiole-4,5-dithiolato)₂] 、 [Pd(N,N'-dimethylpiperazine-2,3-dithione)2](BF4)2 以 丙酮 为溶剂， 以89%的产率得到[Pd(dmit)(Me2pipdt)]
  参考文献：
  名称：

  Square-planar d8 metal push–pull dithiolene complexes: Synthesis and characterization of [Pd(Me2pipdt)(dmit)]

  摘要：

  Experimental and theoretical results on the novel [Pd(Me(2)pipdt)(dmit)] complex (1) based on the push Me(2)pipdt (1,4-dimethyl-piperazine-3,2-dithione) and pull dmit (1,3-dithiolo-2-thione-4,5-dithiolato), show that an unbalanced electron distribution at the dithiolene core occurs. The presence of a solvato-chromic absorption at low energy, shifted to higher frequency when compared to the corresponding nickel case, points out that these complexes are potential second-order non-linear chromophores, whose properties are tunable with the metal. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.04.001