[Zn(5-aminotetrazolate)(nicotinato)](n) | 1450617-85-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Zn(5-aminotetrazolate)(nicotinato)](n)
• CAS: 1450617-85-2
• 化学式: CH₂N₅*C₆H₄NO₂*Zn
• 分子量: 271.554
• InChiKey: YYOADWFYTHCYAE-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  异烟酸 、 sodium azide 、 zinc(II) nitrate hexahydrate 、 二聚氰胺 以 乙醇 、 水 为溶剂， 以38%的产率得到[Zn(5-aminotetrazolate)(nicotinato)](n)
  参考文献：
  名称：

  Synthesis, crystal structures and properties of three new mixed-ligand d10 metal complexes constructed from pyridinecarboxylate and in situ generated amino-tetrazole ligand

  摘要：

  Three new metal-organic frameworks, [Zn(atz)(nic)](n)(1), [Zn(atz)(isonic)](n) center dot nHisonic(2) and [Cd(atz) (isonic)](n)(3) (Hnic = nicotinic acid, Hisonic = isonicotinic acid), have been firstly synthesized by employing mixed-ligand of pyridinecarboxylate with the in situ generated ligand of 5-aminotetrazolate(atz(-)), and characterized by elemental analysis, IR spectroscopy, TGA and single crystal X-ray diffraction. The results revealed that 1 presents a two-dimensional (2D) "sql" topological network constructed from the linear chain Subunit of Zn(nic)(2) and atz(-) ligand. A remarkable feature of 2 is a 2-fold interpenetrated diamondoid network with free Hisonic molecules locating in the channels formed by the zigzag chain subunits of Zn(isonic)(2). Complex 3 is a 3D non-interpenetrated pillared framework constructed from the double chain Subunits of Cd-COO--Cd. It possesses a rarely observed (4,6)-connected "fsc" topology. The thermal stabilities and fluorescent properties of the complexes were investigated. All of these complexes exhibited intense fluorescent emissions in the solid state at room temperature. (C) 2009 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2009.04.034