[Ni(II)(N'-(1-(thiophen-2-yl)ethylene)benzohydrazide(-H))2] | 1361111-03-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ni(II)(N'-(1-(thiophen-2-yl)ethylene)benzohydrazide(-H))2]
• CAS: 1361111-03-6；194545-04-5
• 化学式: C₂₆H₂₂N₄NiO₂S₂
• 分子量: 545.308
• InChiKey: OQNZVNJWJQKHOO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dibromobis(triphenylphosphine)nickel(II) 、 (E)-N'-(1-(thiophen-2-yl)ethylidene)benzohydrazide 在 Et₃N 作用下， 以 四氢呋喃 为溶剂， 以60%的产率得到[Ni(II)(N'-(1-(thiophen-2-yl)ethylene)benzohydrazide(-H))2]
  参考文献：
  名称：

  Synthesis, crystal structures and use in ethylene oligomerization catalysis of novel mono- and dinuclear nickel complexes supported by (E)-N′-(1-(thiophen-2-yl)ethylidene)benzohydrazide ligand

  摘要：

  The coordination chemistry of Ni-II supported by (E)-N'-(1-(thiophen-2-yl)ethylidene)benzohydrazide ligand (HL) is reported and discussed. The crystal structure of ligand HL has been determined as well as those of three new Ni-II complexes (Ni(HL)(2)Br-2, NiL2 and mu-aquo-Ni2L4). The pseudo-octahedral bis(chelate) Ni(II) complex 2 (NiL2), in which unexpected and singular Ni center dot center dot center dot S interaction is observed, was evaluated as catalyst for the oligomerization of ethylene and found to provide ethylene dimers and trimers as primary products with a turnover frequency (TOF) of 31200 mol of C2H4 per mol. of Ni and per hour. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.11.009