bis(2-aminocyclopentene-1-dithiocarboxylato)zinc(II) | 100011-97-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 有机二硫化物
• 英文名称: bis(2-aminocyclopentene-1-dithiocarboxylato)zinc(II)
• CAS: 100011-97-0；32647-18-0
• 化学式: C₁₂H₁₆N₂S₄Zn
• 分子量: 381.926
• InChiKey: MOUNBYWKWVQFRT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.51
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.04
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  bis(2-aminocyclopentene-1-dithiocarboxylato)zinc(II) 以 further solvent(s) 为溶剂， 生成 zinc sulfide
  参考文献：
  名称：

  Effective photocatalytic degradation of organic pollutant by ZnS nanocrystals synthesized via thermal decomposition of single-source precursor

  摘要：

  2-Aminocyclopentene-1-dithiocarboxylate complex of zinc(II) has been synthesized and found to be an effective single-source precursor for the preparation of ZnS NCs (rod and sphere) by the use of ethylenediamine and hexadecylamine as structure directing solvents. Structural characterizations were carried out using XRD, TEM and BET measurements and the optical properties by UV-Vis and PL spectroscopic techniques. The prepared ZnS NCs show effective photocatalytic activity towards the degradation of Rose Bengal dye (RB) under light irradiation for their probable application in waste water treatment. The degradation mechanism of RB dye under light irradiation is established by terephthalic acid photoluminescence probing technique. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.06.029
• 作为产物：
  描述：

  2-氨基-1-环戊烯-1-二硫代甲酸 、 zinc(II) chloride 以 乙醇 为溶剂， 以78%的产率得到bis(2-aminocyclopentene-1-dithiocarboxylato)zinc(II)
  参考文献：
  名称：

  Effective photocatalytic degradation of organic pollutant by ZnS nanocrystals synthesized via thermal decomposition of single-source precursor

  摘要：

  2-Aminocyclopentene-1-dithiocarboxylate complex of zinc(II) has been synthesized and found to be an effective single-source precursor for the preparation of ZnS NCs (rod and sphere) by the use of ethylenediamine and hexadecylamine as structure directing solvents. Structural characterizations were carried out using XRD, TEM and BET measurements and the optical properties by UV-Vis and PL spectroscopic techniques. The prepared ZnS NCs show effective photocatalytic activity towards the degradation of Rose Bengal dye (RB) under light irradiation for their probable application in waste water treatment. The degradation mechanism of RB dye under light irradiation is established by terephthalic acid photoluminescence probing technique. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.06.029