tributoxy(methoxy)titanium | 109127-33-5

• 分子结构分类: 有机化合物
• 英文名称: tributoxy(methoxy)titanium
• 英文别名: tetrabutyl titanate
• CAS: 109127-33-5
• 化学式: C₁₃H₃₀O₄Ti
• 分子量: 298.259
• InChiKey: VPLHNOHKKDGNMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18.0
• 可旋转键数：
  13.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.92
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  tributoxy(methoxy)titanium 在 氢氟酸 作用下， 反应 24.0h， 生成 dioxide titanium
  参考文献：
  名称：

  用于人工光合作用的半导体/共价有机骨架Z型异质结

  摘要：

  提出了一种将晶体共价有机骨架与半导体共价连接的策略，以创建用于人工光合作用的稳定的有机-无机Z型异质结。一系列COF-半导体Z-方案的光催化剂组合水氧化半导体（的TiO 2，铋2 WO 6，和的α-Fe 2 ö 3与CO）2还原的COF（COF-316/318）中合成并表现出高的光催化CO 2到CO的转换效率（高达69.67μmolg -1  h -1），其中H 2 O作为气固CO 2中的电子给体减少，而无需其他光敏剂和牺牲剂。这是利用Z方案进行人工光合作用的共价键合COF /无机半导体系统的首次报道。实验和计算证实了通过共价偶联有效进行的半导体到COF的电子转移，导致电子在COF的氰基/吡啶部分中积累以进行CO 2还原，并在半导体中的空穴中进行H 2 O氧化，从而模仿了自然光合作用。

  DOI：

  10.1002/anie.202000929
• 作为产物：
  描述：

  tetrabutoxytitanium 、 甲醇 以 甲醇 为溶剂， 生成 tributoxy(methoxy)titanium
  参考文献：
  名称：

  Study of intermolecular interactions in an equilibrium system in the catalytic transesterification of esters 3. Interaction of tetrabutyl titanate with alcohols from ir and NMR spectroscopic data

  摘要：

  The reactions of tetrabutyltitanate (TBT) with alcohols have been studied using IR, Raman, and NMR spectroscopy. It has been shown that TBT is associated and has a centrosymmetrical structure. In nonpolar solvents (CCl4, cyclohexane) the associates do not break down on dilution. In the presence of butanol breakdown of the associates occurs accompanied by a reduction in the number, and even the disappearance, of bridging alkoxy groups. C-13 NMR results show that in mixtures of TBT and alcohols two types of exchange reaction take place simultaneously: between terminal and bridging alkoxy groups, and between TBT and the alcohol. In the case of n-BuOH the first type of exchange is retarded as the temperature is reduced to 283 K but the second is unaffected right down to 213 K. IR results show that alcohols form complexes with TBT in which the alcohol is bonded by a H-bond to the oxygen of the alkoxy group of the TBT and by the oxygen atom to the Ti of a second molecule of TBT. For the exchange reaction between TBT radicals and n-C7H15OH in a binary mixture of 1:1 composition at 293 K, IR spectroscopy showed the degree of conversion in terms of alcohol to be 65% and the equilibrium constant K(e) = 3.4. For MeOH in CCl4 solution the conversion amounted to around 100%.

  DOI：

  10.1007/bf00960400