(3,1)-tetrakis(1-tert-butyl-imidazole-2-thiolate)palladium(II)-acetonitrile | 1192013-21-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (3,1)-tetrakis(1-tert-butyl-imidazole-2-thiolate)palladium(II)-acetonitrile
• CAS: 1192013-21-0
• 化学式: C₂H₃N*C₂₈H₄₄N₈Pd₂S₄
• 分子量: 874.867
• InChiKey: YUBVRVYMSJIUGG-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  乙腈 、 palladium diacetate 、 tetrakis(1-tert-butyl-imidazole-2-thione)nickel(II) diiodide 在 KH 作用下， 以 氘代乙腈 为溶剂， 生成 (3,1)-tetrakis(1-tert-butyl-imidazole-2-thiolate)palladium(II)-acetonitrile
  参考文献：
  名称：

  2-Mercapto-1-t-butylimidazolyl as a bridging ligand: Synthesis and structural characterization of nickel and palladium paddlewheel complexes

  摘要：

  Nickel and palladium paddlewheel complexes that feature 2-mercapto-1-t-butylimidazolyl (mim(But)) bridging ligands, namely Ni-2[mim(But)](4) and Pd-2[mim(But)](4), have been synthesized and structurally characterized by X-ray diffraction. Since the mimBut ligand bridges in an asymmetric manner via a sulfur and nitrogen donor, paddlewheel compounds of the type M-2[mim(But)](4) may exist as isomers that are distinguished by the relative orientations of the ligands. In this regard, the (4,0)-Ni-2[mim(But)](4) and trans-(2,2)-Ni-2[mim(But)](4) isomers have been isolated for the nickel system, while the (4,0)-Pd-2[mim(But)](4) and (3,1)-Pd-2[mim(But)](4) isomers have been isolated for the palladium system. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.05.025