hexachloro(μ-disulfido)(μ-tetrahydrothiophene)bis(tetrahydrothiophene)dimolybdenum(IV) | 155342-91-9

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: hexachloro(μ-disulfido)(μ-tetrahydrothiophene)bis(tetrahydrothiophene)dimolybdenum(IV)
• CAS: 155342-91-9
• 化学式: C₁₂H₂₄Cl₆Mo₂S₅
• 分子量: 733.251
• InChiKey: UMEJEXHZSZWGBE-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  9.97
• 重原子数：
  25.0
• 可旋转键数：
  2.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  四氢噻吩 、 以 二氯甲烷 为溶剂， 以60%的产率得到hexachloro(μ-disulfido)(μ-tetrahydrothiophene)bis(tetrahydrothiophene)dimolybdenum(IV)
  参考文献：
  名称：

  Disulfur-bridged complexes of molybdenum. Crystal structure of the dimolbdenum(IV) complex [{MoCl₃(C₄H₈S)}₂(µ-S₂)(µ-C₄H₈S)] and of the Mo^IVMo^Vcomplex [(Me₂S)₂Cl₂Mo({µ-S₂)(µ-S)MoCl₃(SMe₂)]

  摘要：

  Treatment of [Mo(CO)6] with S2Cl2 gave a very dark green material of empirical formula Mo2S2Cl6.CH2Cl2 1 which, on reaction with L, gave green [{MoCl3(L)}2(mu-S2)(mu-L)] (L = C4H8S 2a, PhCH2SMe 2b or C4H8O 2c), and with SMe2 gave the novel, brown, unsymmetrical, mixed-oxidation-state complex [(Me2S)2Cl2Mo(mu-S2)(mu-S)MoCl3(SMe2)] 3. The structures of 2a and 3 have been established by X-ray crystallography. Compounds 2a-2c are diamagnetic and NMR data have been obtained, whereas 3 is paramagnetic and shows, in a CH2Cl2 glass at 40 K, a broad, roughly axial EPR resonance with g(max) at 1.94.

  DOI：

  10.1039/dt9940000621

文献信息

• A series of µ-disulphido–dimolybdenum(<scp>IV</scp>) complexes: X-ray structure of the novel (µ-tetrahydrothiophene) complex [(C₄H₈S)Cl₃Mo(µ-S₂)(µ-C₄H₈S)MoCl₃(C₄H₈S)]
  作者：David L. Hughes、Raymond L. Richards、Caroline Shortman

  DOI：10.1039/c39860001731

  日期：——

  The complexes [Mo2(µ-S2)Cl6L3](L = C4H8O or C4H8S); [Mo2(µ-S2)Cl6L2](L = C4H8O, MeCN, 4-MeOC6H4CN, 2-MeC5H4N, or 2,6-Me2C5H3N) and [PPh4]2[Mo2S2Cl8] have been prepared; the X-ray structure of [(C4H8S)Cl3Mo(µ-S2)(µ-C4H8S)MoCl3(C4H8S)] shows and unusual bridging C4H8S ligand.

  配合物 [Mo2(µ-S2)Cl6L3](L = C4H8O 或 C4H8S)； [Mo2(μ-S2)Cl6L2](L = 、MeCN、4-MeOC6H4CN、2-MeC5H4N 或 2,6-Me2C5H3N) 和 [PPh4]2[Mo2S2Cl8] 已制备； [( )Cl3Mo(μ-S2)(μ- )MoCl3( )]的X射线结构显示出不寻常的桥连 配体。