copper(1+);cyclopenta-1,3-diene;1-(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)-N-[2-[(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)methylideneamino]ethyl]methanimine;iron(2+);trifluoromethanesulfonate | 177339-43-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: copper(1+);cyclopenta-1,3-diene;1-(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)-N-[2-[(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)methylideneamino]ethyl]methanimine;iron(2+);trifluoromethanesulfonate
• CAS: 177339-43-4
• 化学式: CF₃O₃S*C₄₈H₄₂Fe₂N₂P₂*Cu
• 分子量: 1033.13
• InChiKey: VRQKHMIEUDLKCO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(I) trifluoromethanesulfonate benzene 、 cyclopenta-1,3-diene;1-(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)-N-[2-[(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)methylideneamino]ethyl]methanimine;iron(2+) 以 乙腈 为溶剂， 以84%的产率得到copper(1+);cyclopenta-1,3-diene;1-(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)-N-[2-[(5-diphenylphosphanylcyclopenta-1,3-dien-1-yl)methylideneamino]ethyl]methanimine;iron(2+);trifluoromethanesulfonate
  参考文献：
  名称：

  Asymmetric synthesis of a chiral tetradentate ligand based on a bis[diphenylphosphinoferrocenyl] moiety. Electrochemical behavior of free ligand and its RuII and CuI complexes

  摘要：

  alpha-diphenylphosphino carboxaldehyde 4, prepared by asymmetric synthesis, was reacted with ethane diamine to give bisimine bisphosphine 5. Ruthenium(II) complex 6 and copper(I) complex 8 were easily formed and their electrochemical properties studied.

  DOI：

  10.1016/0022-328x(95)05968-u