Pd(OAc)2(pyiu(Cy)) | 1372712-47-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Pd(OAc)2(pyiu(Cy))
• 英文别名: [Pd(OAc)2(1,3-dicyclohexyl-2-((pyridin-2-yl)methyl)isourea
• CAS: 1372712-47-4
• 化学式: C₂₃H₃₅N₃O₅Pd
• 分子量: 539.968
• InChiKey: XLFJGNRXBNADGX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,3-dicyclohexyl-2-((pyridin-2-yl)methyl)isourea 、 palladium diacetate 以 二氯甲烷 为溶剂， 以90%的产率得到Pd(OAc)2(pyiu(Cy))
  参考文献：
  名称：

  Synthesis and characterization of novel pyridine–isourea complexes of Pd(II)

  摘要：

  New neutral palladium(II) complexes having formula PdCl2(pyiu(Pr)), PdCl2(pyiu(Cy)), Pd(OCOCH3)(2)(pyiu(Pr)), Pd(OCOCH3)(2)(pyiu(Cy)), Pd(CH3)Cl(pyiu(Pr)) and Pd(CH3)(2)(pyiu(Pr)), where pyiu and pyiu(Cy) are the novel ligands 1,3-diisopropyl-2-((pyridin-2-yl)methyl)isourea and 1,3-dicyclohexy1-2-((pyridin-2-yl)methyl) isourea, were synthesized and characterized. These neutral ligands act as bidentate and coordinate the palladium center through the pyridine N-atom and one of the nitrogen atoms of the isourea dent, as deducted by variable-temperature NMR experiments and DFT calculations and observed by X-ray diffraction experiments on the complex PdCl2(pyiu(Cy)). (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.02.014