| 148575-01-3

• CAS: 148575-01-3
• 化学式: C₂₂H₁₉BrIMoN₂O₃SSb
• 分子量: 815.969
• InChiKey: UJSFHXAFAVEDFW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 三苯基锑 、 硫脲 以 二氯甲烷 为溶剂， 以54%的产率得到
  参考文献：
  名称：

  The preparation and reactions with donor ligands of [MoBrI(CO)3(NCMe)2]

  摘要：

  Equimolar quantities of fac-[Mo(CO)3(NCMe)3] {prepared in situ by reacting [Mo(CO)6] in refluxing acetonitrile for 24 h} and BrI react at 0-degrees-C to give the seven-coordinate complex [MoBrI(CO)3(NCMC)2] (1). Complex 1 reacts with 1 equivalent of L (L = PPh3, ASPh3 or SbPh3) to initially give the mono(acetonitrile) complexes [MoBrI(CO)3(NCMe)L], which subsequently dimerize to afford [Mo(mu-I)Br(CO)3L]2. Reaction of 1 with 2 equivalents of L (L = PPh3, AsPh3 Or SbPh3) gives the bis(ligand) compounds [MoBrl(CO)3L2]. The preparation and characterization of a series of new mixed-ligand complexes [MoBrl(CO)3LL'] [L = PPh3, L' = AsPh3; L = PPh3, L' = SbPh3; L = AsPh3, L' = SbPh3; L = PPh3, AsPh3 and SbPh3; L' = SPPh3, SC(NH2)2 and SC(NMe2)2] are also described. Equimolar quantities of LL [LL = Ph2P(CH2)nPPh2 (n = 1-3); 1,10-phen] and [MoBrl(CO)3(NCMe)2] react to afford the acetonitrile displaced products [MoBrl(CO)3(LL)] in high yield. The synthesis of the novel, dicarbonyl five different ligand compound [MoBrI(CO)2(NCMe)(SbPh3)2] is also reported.

  DOI：

  10.1016/s0277-5387(00)81738-6