4-(diethylamino)-2-isopropoxystyrene | 934165-43-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-(diethylamino)-2-isopropoxystyrene
• 英文别名: (CH2CH)(C3H7O)(C6H3)(4-NEt2)；4-ethenyl-N,N-diethyl-3-propan-2-yloxyaniline
• CAS: 934165-43-2
• 化学式: C₁₅H₂₃NO
• 分子量: 233.354
• InChiKey: UHLOSMYPTIBYOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 、 4-(diethylamino)-2-isopropoxystyrene 在 copper(l) chloride 作用下， 以 二氯甲烷 为溶剂， 以44%的产率得到(Mes2(C3H4N2))Cl2Ru(CH(C6H3)(OC3H7)(4-NEt2))
  参考文献：
  名称：

  New tunable catalysts for olefin metathesis: Controlling the initiation through electronic factors

  摘要：

  Synthesis and screening of catalytic activity of two novel ruthenium carbene complexes 9 and 10 bearing substiments in 2-isopropoxybenzylidene ligand is described. These precatalysts constitute excellent tools for RCM and enyne metathesis by combining high stability with a possibility of their on-demand activation by heat and Bronsted (9) or Lewis acids (10). (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.12.049

文献信息

• Second-order nonlinear optical compound and nonlinear optical element comprising the same
  申请人：NATIONAL INSTITUTE OF INFORMATION AND COMMUNICATIONS TECHNOLOGY

  公开号：US10754064B2

  公开（公告）日：2020-08-25

  Problem to Be Solved: to provide a chromophore having a far superior nonlinear optical activity to conventional chromophores and to provide a nonlinear optical element comprising said chromophore. Solution: a chromophore comprising a donor structure D, a π-conjugated bridge structure B, and an acceptor structure A, the donor structure D comprising an aryl group substituted with a substituted oxy group; and a nonlinear optical element comprising said chromophore.

  有待解决的问题：提供一种发色团，其非线性光学活性远远优于传统发色团，并提供一种包含所述发色团的非线性光学元件。 解决方案：一种发色团，包括供体结构 D、π-共轭桥结构 B 和受体结构 A，供体结构 D 包括被取代氧基取代的芳基；以及一种包含所述发色团的非线性光学元件。
• SECOND-ORDER NONLINEAR OPTICAL COMPOUND AND NONLINEAR OPTICAL ELEMENT COMPRISING THE SAME
  申请人：NATIONAL INSTITUTE OF INFORMATION AND COMMUNICATIONS TECHNOLOGY

  公开号：US20180224577A1

  公开（公告）日：2018-08-09

  Problem to Be Solved: to provide a chromophore having a far superior nonlinear optical activity to conventional chromophores and to provide a nonlinear optical element comprising said chromophore. Solution: a chromophore comprising a donor structure D, a π-conjugated bridge structure B, and an acceptor structure A, the donor structure D comprising an aryl group substituted with a substituted oxy group; and a nonlinear optical element comprising said chromophore.
• US9977150B2
  申请人：——

  公开号：US9977150B2

  公开（公告）日：2018-05-22