| 1430638-99-5

• 分子结构分类: 有机化合物
• CAS: 1430638-99-5
• 化学式: C₄₆H₆₀FeN₂O₂
• 分子量: 728.842
• InChiKey: UHLILOAOKIWYKF-VTRQUILJSA-L

反应信息

• 作为产物：
  描述：

  、 iron(II) chloride 以 四氢呋喃 为溶剂， 反应 12.0h， 以69%的产率得到
  参考文献：
  名称：

  Molecular structure and spectroscopy of divalent first row transition metals, Mn–Zn, with salicylaldiminate ligands

  摘要：

  The synthesis and spectroscopy of divalent first row transition metals bearing two monoanionic salicylaldiminate ligands is reported. The reaction of MnCl2, FeCl2, CoBr2, 1,2-(Ph2PCH2CH2PPh2)NiCl2, and CuCl2 with 2 equiv. of the alkali metal salt of [(OC6H2Bu2C)-Bu-t(H)=N(C6H3Me2)](1-) produces the corresponding M[(OC6H2Bu2C)-Bu-t(H)=N(C6H3Me2)](2), M = Mn, Fe, Co, Ni, and Cu. Reaction of ZnEt2 with 2 equiv. of the protonated ligand affords Zn[(OC6H2Bu2C)-Bu-t(H)=N(C6H3Me2)](2). The molecular structure of each complex has been analyzed using IR spectroscopy and X-ray crystallography while UV-Vis, CW-EPR, solution magnetic susceptibilities, and OFT calculations were also used to probe their electronic structure. Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2013.02.011