[Tb(2-(2-(diisopropylamino)-2-oxoethoxy)-N-(pyridin-2-ylmethyl)benzamide)(NO3)3(H2O)] | 1395498-69-7

• 分子结构分类: 有机化合物
• 英文名称: [Tb(2-(2-(diisopropylamino)-2-oxoethoxy)-N-(pyridin-2-ylmethyl)benzamide)(NO3)3(H2O)]
• CAS: 1395498-69-7
• 化学式: C₂₁H₂₉N₆O₁₃Tb
• 分子量: 732.419
• InChiKey: YANMELGPSHSDIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  terbium(III) nitrate hexahydrate 、 2-(2-(diisopropylamino)-2-oxoethoxy)-N-(pyridin-2-ylmethyl)benzamide 、 水 以 乙酸乙酯 为溶剂， 以75%的产率得到[Tb(2-(2-(diisopropylamino)-2-oxoethoxy)-N-(pyridin-2-ylmethyl)benzamide)(NO3)3(H2O)]
  参考文献：
  名称：

  Synthesis, crystal structures and luminescence properties of lanthanide complexes with a tridentate salicylamide-type ligand

  摘要：

  Six lanthanide nitrato complexes [Ln = La (1), Nd (2), Eu (3), Gd (4), Tb (5), Er (6)] with a tridentate salicylamide-type ligand, 2-(2-(diisopropylamino)-2-oxoethoxy)-N-(pyridin-2-ylmethyl)benzamide (L), have been synthesized. All complexes were characterized by elemental analysis, IR, TGA and conductivity measurements. The structures of 2, 3 and 4 were determined by X-ray single-crystal diffraction and their general formulae were shown to be [LnL(NO3)(3)(H2O)]center dot CH3CN. These data indicate the tridentate salicylamide- type ligand could effectively chelate the lanthanide ions to conform to a 1:1 metal-to-ligand stoichiometry. The luminescence properties of the europium and terbium complexes were also investigated. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.05.009