2-[[(Butylthio)thioxomethyl]thio]butanedioic acid | 558484-22-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-[[(Butylthio)thioxomethyl]thio]butanedioic acid
• 英文别名: 2-butylsulfanylcarbothioylsulfanylbutanedioic acid
• CAS: 558484-22-3
• 化学式: C₉H₁₄O₄S₃
• 分子量: 282.4
• InChiKey: DEDBHVFXKCVOCV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  157
• 氢给体数：
  2
• 氢受体数：
  7

文献信息

• Aqueous dispersions of polymer particles
  申请人：Such Henry Christopher

  公开号：US20060223936A1

  公开（公告）日：2006-10-05

  The invention provides a method for preparing an aqueous dispersion of polymer particles comprising the following steps: (i) preparing a dispersion having a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and an amphiphilic RAFT agent as a stabiliser for said organic phase, and (ii) polymerising said one or more ethylenically unsaturated monomers under the control of said amphiphilic RAFT agent to form said aqueous dispersion of polymer particles, novel amphiphilic RAFT agents for use in this method, novel RAFT agents useful in making these amphiphilic RAFT agents and methods for their manufacture.

  本发明提供了一种制备聚合物颗粒水分散液的方法，包括以下步骤：(i)制备一个连续的水相分散体系，其中包括一个或多个乙烯基不饱和单体的分散有机相，并且含有一种两亲性RAFT剂作为有机相的稳定剂，以及(ii)在该两亲性RAFT剂的控制下聚合该一种或多种乙烯基不饱和单体，以形成所述聚合物颗粒的水分散液，以及在该方法中使用的新型两亲性RAFT剂，用于制备这些两亲性RAFT剂的新型RAFT剂和它们的制备方法。
• AQUEOUS DISPERSIONS OF POLYMER PARTICLES
  申请人：SUCH Christopher Henry

  公开号：US20100227975A1

  公开（公告）日：2010-09-09

  The invention provides a method for preparing an aqueous dispersion of polymer particles comprising the following steps: (i) preparing a dispersion having a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and an amphiphilic RAFT agent as a stabiliser for said organic phase, and (ii) polymerising said one or more ethylenically unsaturated monomers under the control of said amphiphilic RAFT agent to form said aqueous dispersion of polymer particles, novel amphiphilic RAFT agents for use in this method, novel RAFT agents useful in making these amphiphilic RAFT agents and methods for their manufacture.

  本发明提供了一种制备聚合物颗粒水分散液的方法，包括以下步骤：(i)制备一种具有连续水相、分散的有机相，其中包括一种或多种乙烯基不饱和单体，以及一种防止有机相稳定剂的亲疏性RAFT剂，(ii)在亲疏性RAFT剂的控制下聚合所述一种或多种乙烯基不饱和单体，以形成所述聚合物颗粒的水分散液。本发明还提供了用于该方法的新型亲疏性RAFT剂，用于制备这些亲疏性RAFT剂的新型RAFT剂以及其制造方法。
• BLOCK COPOLYMER AND METHOD FOR PRODUCING BLOCK COPOLYMER
  申请人：Denka Company Limited

  公开号：EP3604367A1

  公开（公告）日：2020-02-05

  To provide a block copolymer that comprises an aromatic vinyl compound polymer and a chloroprene polymer, has a number average molecular weight of 100,000 or more, is preferred for a rubber composition and an adhesive composition, and is suitable for industrial production. A block copolymer comprises at least one aromatic vinyl compound polymer block and at least one chloroprene polymer block, has a functional group with a structure represented by Chemical Formula (1) or (2), and has a number average molecular weight of 100,000 or more. The chloroprene polymer block has a number average molecular weight of 80,000 or more in total. (In Chemical Formula (1), R1 is hydrogen, chlorine, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclyl group)

  提供一种嵌段共聚物，它由芳香族乙烯基化合物聚合物和氯丁二烯聚合物组成，具有 100,000 或以上的平均分子量，优选用于橡胶组合物和粘合剂组合物，并适合工业生产。嵌段共聚物由至少一种芳香族乙烯基化合物聚合物嵌段和至少一种氯丁二烯聚合物嵌段组成，具有化学式（1）或（2）所代表结构的官能团，平均分子量大于等于 100,000。氯丁二烯聚合物嵌段的总平均分子量为 80,000 或以上。 (在化学式（1）中，R1 是氢、氯、取代或未取代的烷基、取代或未取代的烯基、取代或未取代的芳基或取代或未取代的杂环基）。
• CHLOROPRENE POLYMER AND PRODUCTION METHOD THEREFOR
  申请人：Denka Company Limited

  公开号：EP3656795A1

  公开（公告）日：2020-05-27

  Provided is a chloroprene-based polymer having an industrially applicable sufficient molecular weight and capable of obtaining a vulcanized rubber excellent in durability and fatigue endurance and an adhesive excellent in layer separation resistance. A chloroprene-based polymer having a number average molecular weight Mn of 150000 to 300000 and comprising a functional group of a structure represented by the general formula (1) or (2) below: (wherein in the general formula (1), R1 shows hydrogen, chlorine, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclyl group.)

  本发明提供了一种氯丁二烯基聚合物，该聚合物具有适用于工业的足够分子量，能够获得耐久性和耐疲劳性优异的硫化橡胶以及耐层间分离性优异的粘合剂。一种氯丁二烯基聚合物，其数均分子量 Mn 为 150000 至 300000，并包含由以下通式 (1) 或 (2) 所代表的结构的官能团： (其中在通式(1)中，R1 表示氢、氯、取代或未取代的烷基、取代或未取代的烯基、取代或未取代的芳基或取代或未取代的杂环基)。
• POLYMER MANUFACTURING METHOD
  申请人：Denka Company Limited

  公开号：EP3660057A1

  公开（公告）日：2020-06-03

  The present invention provides a polymer having a narrow molecular weight distribution by living radical polymerization. A polymer manufacturing method comprising a step of performing living radical polymerization using 0.005 to 0.5 parts by mass of an oxygen radical scavenger per 100 parts by mass of a radical polymerizable monomer.

  本发明通过活自由基聚合提供了一种具有窄分子量分布的聚合物。 一种聚合物制造方法，包括以下步骤：每 100 份可自由基聚合单体使用 0.005 至 0.5 份（质量份）氧自由基清除剂进行活自由基聚合。