[Pd(CN)(μ-N-(2-mercaptoethyl)-3,5-dimethylpyrazole)]2 | 1147126-01-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Pd(CN)(μ-N-(2-mercaptoethyl)-3,5-dimethylpyrazole)]2
• CAS: 1147126-01-9
• 化学式: C₁₆H₂₂N₆Pd₂S₂
• 分子量: 575.363
• InChiKey: WQDGGKHXJQJUCL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  sodium cyanide 、 [Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))Cl]2 在 AgBF₄ 作用下， 以 甲醇 、 二氯甲烷 、 乙腈 为溶剂， 以88%的产率得到[Pd(CN)(μ-N-(2-mercaptoethyl)-3,5-dimethylpyrazole)]2
  参考文献：
  名称：

  Reactivity of [PdCl(μ-med)]2 with monodentate anionic ligands. Structure of dinuclear complexes [Pd(X)(μ-med)]2 (X=SCN−, ). [Hmed=N-2-mercaptoethyl)-3,5-dimethylpyrazole]

  摘要：

  The reaction of the complex [PdCl(mu-med)](2) (Hmed = N-(2-mercaptoethyl)-3,5-dimethylpyrazole) with NaCN, NaSCN or NaN3 in presence of AgBF4, yielded complexes with formula [Pd(X)(mu-med)](2) (X = CN (1), SCN (2) or N-3-(3)). These complexes have been characterised by elemental analyses, conductivity measurements, IR and NMR spectroscopies. X-ray crystal structures of [Pd(SCN)(mu-med)](2) center dot 0.5CH(3)CN and [Pd(N-3)(mu-med)](2), are presented. These complexes consist of thiolate-bridged dinuclear units. Each Pd(II) is coordinated by a pyrazole nitrogen, two bridging sulfur atoms and one SCN (2) or N-3-(3) anion. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.07.022