(tri-tert-butoxysilanethiolato)(2-isopropylimidazole)(acetylacetonato)Zn | 1220531-49-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (tri-tert-butoxysilanethiolato)(2-isopropylimidazole)(acetylacetonato)Zn
• CAS: 1220531-49-6
• 化学式: C₂₃H₄₄N₂O₅SSiZn
• 分子量: 554.154
• InChiKey: RVLXKHCPNFGKGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-异丙基咪唑 、 tri-tert-butoxysilanethiol 、 zinc acetylacetonate hydrate 以 甲醇 、 乙腈 为溶剂， 以23%的产率得到(tri-tert-butoxysilanethiolato)(2-isopropylimidazole)(acetylacetonato)Zn
  参考文献：
  名称：

  Novel zinc complexes with acetyloacetonate, imidazole and thiolate ligands: Crystal structure of a zinc complex of relevance to farnesyl transferase

  摘要：

  New zinc(II) complex 1 with three different ligands: acetyloacetonate, tri-tert-butoxysilanethiolate and neutral 2-isopropylimidazole has been obtained and characterized by X-ray diffraction. It is the first example of a mononuclear zinc(II) complex mimicking the active site of farnesyl transferase. (2-Isopropylimidazole)bis(acetylacetonato)zinc(II) 2 is also described as an intermediate product of the reaction leading to the formation of 1. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.06.025