5-((3-chlorophenyl)amino)-9-(diethylamino)benzo[a]phenoxazin-7-ium hydrosulfate | 1248337-01-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 5-((3-chlorophenyl)amino)-9-(diethylamino)benzo[a]phenoxazin-7-ium hydrosulfate
• CAS: 1248337-01-0
• 化学式: C₂₆H₂₃ClN₃O*HO₄S
• 分子量: 526.013
• InChiKey: JMZHJRBUOMTLLU-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  5-((3-chlorophenyl)imino)-N,N-diethyl-5H-benzo[a]phenoxazin-9-amine 在 硫酸 作用下， 以 乙醇 、 氯仿 为溶剂， 反应 0.5h， 以83%的产率得到5-((3-chlorophenyl)amino)-9-(diethylamino)benzo[a]phenoxazin-7-ium hydrosulfate
  参考文献：
  名称：

  The synthesis and third-order nonlinear optical properties of resonance Benzo[a]phenoxazinium salts

  摘要：

  The third-order nonlinear optical properties of a series of resonance benzo[a]phenoxazinium salts in acetic acid solution were studied using the Z-scan technique employing a Nd YAG nanosecond laser at 532 nm The compounds displayed strong reverse absorption with third-order nonlinear optical coefficients of 042-1.20 x 10(-11) esu and second hyperpolarizabilities of 2 75-7.29 x 10(-29) esu, respectively. Quantum chemical calculations showed that the compound with more stable highest occupied molecular orbital energy also displayed highest second hyperpolarizability (C) 2010 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.dyepig.2010.04.014