1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6 | 1227059-50-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6
• 英文别名: 33H-4,23-(Methano(1,3)benzenomethano)-28,32-metheno-27H-tribenzo(h,q,z)(1,4,7,10,13,16)hexaoxacycloheptacosin, 34,37-bis((3,7-dimethyloctyl)oxy)-6,7,9,10,17,18,20,21-octahydro-, stereoisomer；47,48-bis(3,7-dimethyloctoxy)-3,6,9,16,19,22-hexaoxaheptacyclo[22.15.7.130,34.141,45.02,36.010,15.023,28]octatetraconta-1(39),2(36),10,12,14,23(28),24,26,30,32,34(48),37,41(47),42,44-pentadecaene
• CAS: 1227059-50-8
• 化学式: C₆₂H₈₂O₈
• 分子量: 955.328
• InChiKey: OTNJLISBEVSKFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.9
• 重原子数：
  70
• 可旋转键数：
  16
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  73.8
• 氢给体数：
  0
• 氢受体数：
  8

文献信息

• EXTRACTANT COMPOSITIONS FOR CO EXTRACTING CESIUM AND STRONTIUM, A METHOD OF SEPARATING CESIUM AND STRONTIUM FROM AN AQUEOUS FEED, CALIXARENE COMPOUNDS, AND AN ALCOHOL MODIFIER
  申请人：PETERMAN DEAN R.

  公开号：US20100116749A1

  公开（公告）日：2010-05-13

  A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4′,4′,(5′)-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4] arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arene-benzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4] arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.

  一种混合萃取剂溶剂，其中包括至少一种二烷氧基卡利克斯[4]芳基冠醚-6化合物，4′,4′,(5′)-双-(叔丁基二环己烷)-18-冠-6，至少一种改性剂，以及可选的稀释剂。二烷氧基卡利克斯[4]芳基冠醚-6化合物是1,3-交替-25,27-二(辛氧基)卡利克斯[4]芳基冠醚-6，1,3-交替-25,27-二(癸氧基)卡利克斯[4]芳基冠醚-6，1,3-交替-25,27-二(十二烷氧基)卡利克斯[4]芳基冠醚-6，1,3-交替-25,27-二(2-乙基己基-1-氧基)卡利克斯[4]芳基冠醚-6，1,3-交替-25,27-二(3,7-二甲基辛基-1-氧基)卡利克斯[4]芳基冠醚-6，1,3-交替-25,27-二(4-丁基辛基-1-氧基)卡利克斯[4]芳基冠醚-6，或其组合。改性剂是一种一次醇。还公开了一种从水性进料中分离铯和锶的方法，以及二烷氧基卡利克斯[4]芳基冠醚-6化合物和醇改性剂。
• US8158088B2
  申请人：——

  公开号：US8158088B2

  公开（公告）日：2012-04-17