dichloroiridium(1+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;trichlororuthenium;triphenylarsane | 781640-72-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: dichloroiridium(1+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;trichlororuthenium;triphenylarsane
• CAS: 781640-72-0
• 化学式: C₂₀H₃₀Cl₃Ir₂*C₃₆H₃₀As₂Cl₇Ru₂
• 分子量: 1824.05
• InChiKey: KERNTRPJVUJYHN-UHFFFAOYSA-D

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 trichlorobis(triphenylarsine)(methanol)ruthenium(III) 以 further solvent(s) 为溶剂， 生成 dichloroiridium(1+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;triphenylarsane 、 dichloroiridium(1+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;trichlororuthenium;triphenylarsane
  参考文献：
  名称：

  Syntheses and structures of homo- and heterobimetallic, chloro-bridged complexes containing the RuCl 3 (AsPh 3 ) n fragment ( n =1, 2)

  摘要：

  The reaction of [RuCl3(AsPh3)(2)(MeOH)] with the dimeric complexes [(cod)RhCl](2), [(ppy)RhCl](2) (ppy = cyclometalated 2-phenylpyridine), [(cymene)RuCl2](2) and [CP*MCl2](2) (M = Rh, Ir) has been investigated. The structure of the resulting products was shown to depend on the reaction partner. Whereas for the rhodium complexes [(cod)RhCl](2) and [(ppy)RhCl](2), heterobimetallic compounds with two halogeno-bridges were found, the reactions with the halfsandwich complexes [(cymene)RuCl2](2) and [CP*MCl2](2) gave triply bridged products with concomitant formation of mononuclear [(pi-ligand)MCl2(AsPh3)] side products. The new complexes were all characterized by single crystal X-ray analysis. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.03.022