Cyclic polycarbonate mixtures containing units derived from spirobiindane bisphenols, preferably 6,6ʹ-dihydroxy-3,3,3ʹ,3ʹ-tetramethylspirobiindane, are prepared from the corresponding bischloroformates or mixtures thereof with bisphenols. They may be homopolymeric or copolymeric; cyclic oligomer mixtures are preferred. Such oligomers may be converted to linear polycarbonates having high glass transition temperatures.
环状聚
碳酸酯混合物含有螺双
茚二
酚衍生单元,最好是 6,6ʹ-二羟基-3,3,3ʹ,3ʹ-四甲基螺双
茚二
酚,由相应的双
氯甲酸酯或其与双
酚的混合物制备。它们可以是均聚物或共聚物;最好是环状低聚物混合物。此类低聚物可转化为具有高
玻璃化转变温度的线性聚
碳酸酯。