4-butyl-3,3,5,5-tetramethyl-thiomorpholine 1,1-dioxide | 52722-93-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 4-butyl-3,3,5,5-tetramethyl-thiomorpholine 1,1-dioxide
• 英文别名: 1-Butyl-2,2,6,6-tetramethyl-1-aza-4-thiacyclohexane-4,4-dioxide；4-butyl-3,3,5,5-tetramethyl-1,4-thiazinane 1,1-dioxide
• CAS: 52722-93-7
• 化学式: C₁₂H₂₅NO₂S
• 分子量: 247.402
• InChiKey: HQHMNCSSALDZHT-UHFFFAOYSA-N

物化性质

• 沸点：
  348.1±35.0 °C(Predicted)
• 密度：
  0.983±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3,3,5,5-tetramethyl-thiomorpholine 1,1-dioxide 、 正溴丁烷 在 氢溴酸 、 3,3,5,5-tetramethyl-thiomorpholine 1,1-dioxide 、 乙醚 、 水 、 Sodium sulfate-III 、 ligroin 作用下， 以 乙醚 为溶剂， 反应 120.0h， 以to obtain 1-butyl-2,2,6,6-tetramethyl-1-aza-4-thiacyclohexane-4,4-dioxide, M.P. 180° C (3)的产率得到4-butyl-3,3,5,5-tetramethyl-thiomorpholine 1,1-dioxide
  参考文献：
  名称：

  1-Aza-4-thiacyclohexane-4,4-dioxide derivatives

  摘要：

  新的1-aza-4-thiacyclohexane-4,4-dioxide衍生物可以单独或与其他稳定剂结合使用来稳定有机材料。这些新化合物是通过将取代的二烯丙基硫醚与氨、胺或肼反应而制备的。

  公开号：

  US04061631A1

文献信息

• 1-Aza-4-thiacyclohexane-4,4-dioxide derivatives and their use as agents
  申请人：Ciba-Geigy Corporation

  公开号：US03943098A1

  公开（公告）日：1976-03-09

  New 1-aza-4-thiacyclohexane-4,4-dioxide derivatives are used alone or in combination with other stabilizers for stabilizing organic materials. The new compounds are prepare by reacting substituted diallylsulfides with ammonia, amines or hydrazines.

  新的1-aza-4-thiacyclohexane-4,4-二氧化物衍生物被单独或与其他稳定剂结合使用来稳定有机材料。新化合物是通过将取代的二烯基硫醚与氨、胺或肼反应制备而成。
• NEAR-INFRARED-ABSORBING MATERIAL AND NEAR-INFRARED-ABSORBING FILTER
  申请人：KIMURA Keizo

  公开号：US20080073626A1

  公开（公告）日：2008-03-27

  The invention provides a near-infrared-absorbing material comprising at least one first compound selected from the group consisting of a singlet oxygen scavenger, a radical trapping agent and an antioxidant and at least one second compound represented by the following formula (II-1) or (II-2).
• ULTRAVIOLET ABSORBENT COMPOSITION
  申请人：Hanaki Naoyuki

  公开号：US20100130638A1

  公开（公告）日：2010-05-27

  An ultraviolet absorbent composition, containing an ultraviolet absorbent represented by formula (2) or (B-I), and a compound represented by formula (TS-I) or (TS-II): wherein A21, A22 and XB1 to XB4 represent a hetero atom; Y21, Y22, RB1 to RB6, R91 to R96, R101 to R104 and X101 represent a hydrogen atom or a substituent; at least one of Y21 and Y22 represents a substituent having a Hammett substituent constant of 0.2 or more; and (B) represents a group of atoms necessary for forming a five- or six-membered ring; —X91- represents —O—, —S—, or —N(—R100)-, in which R100 has the same meaning as R91; all of R91 to R96 and R100 cannot simultaneously represent a hydrogen atom, respectively, and the total number of carbon atoms is 10 or more; and X102 represents a group of hetero atoms necessary for forming a 5- to 7-membered ring.
• NEAR-INFRARED ABSORBING MATERIAL
  申请人：Kimura Keizo

  公开号：US20100224839A1

  公开（公告）日：2010-09-09

  The invention provides a near-infrared absorbing material, including: at least one of at least one singlet oxygen scavengers, at least one radical scavenger, and at least one antioxidant; and at least one near-infrared absorbing compound obtained by oxidation of a compound represented by the following Formula (II). In the formula, R 211 , R 212 , R 221 , R 222 , R 231 , R 232 , R 241 and R 242 independently represent a hydrogen atom or an aliphatic or aromatic group; R 203 , R 213 , R 223 , R 233 and R 243 independently represent a substituent; and n 203 , n 213 , n 223 , n 233 and n 243 independently represent an integer of 0 to 4.
• LIGHTING UNIT COVER
  申请人：Furukawa Kazushi

  公开号：US20110163284A1

  公开（公告）日：2011-07-07

  A lighting unit cover, having a resin composition including ultraviolet absorbent A, the ultraviolet absorbent A being a compound represented by formula (1): in which, Het 1 represents a bivalent five- or six-membered aromatic heterocyclic residue; the aromatic heterocyclic residue may have a substitutent; and R 1a , R 1b , R 1c , R 1d , R 1e , R 1f , R 1g and R 1h each independently represent a hydrogen atom or a monovalent substituent.