trans-dichlorotetrakis(thiazole)rhodium(III) perchlorate * acetonitrile | 149272-34-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: trans-dichlorotetrakis(thiazole)rhodium(III) perchlorate * acetonitrile
• CAS: 149272-34-4
• 化学式: C₂H₃N*C₁₂H₁₂Cl₂N₄RhS₄*ClO₄
• 分子量: 654.833
• InChiKey: QWKKDHZQMWTXRR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  噻唑 、 potassium perchlorate 、 无水氯化铑(III) 以 水 为溶剂， 生成 trans-dichlorotetrakis(thiazole)rhodium(III) perchlorate * acetonitrile
  参考文献：
  名称：

  Structure oftrans-dichlorotetrakis(thiazole)Rh(III) perchlorate�acetonitrile solvate

  摘要：

  The title compound [RhCl2(SNC3H3)4] [ClO4] . CH3CN is monoclinic, with a = 23.791(4), b = 7.253(2), c = 14.498(2) angstrom, beta = 105.24(1)-degrees, V = 2414(1) angstrom3, Z = 4, D(x) = 1.802, mu(MoKalpha) = 13.95 cm-1, F(000) = 1304, T = 298K in space group Cc. The structure was solved by heavy atom and Fourier methods and refined to R = 0.047 for 4742 unique observed reflections. The cation is nearly octahedral, with the cis and trans angles about the Rh in the range from 89.2(2) to 90.8(2)-degrees and 179.4(2) to 180.0(2)-degrees, respectively. Average Rh-Cl and Rh-N bond lengths are 2.337(2) and 2.036(6) angstrom. One of the thiazole ligands showed disorder between the S and one of the C atoms in the ring.

  DOI：

  10.1007/bf01182525