phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II) | 710341-72-3

• 分子结构分类: 有机化合物
• 英文名称: phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)
• CAS: 710341-72-3
• 化学式: C₂₄H₂₄N₂PtS₂
• 分子量: 599.68
• InChiKey: WUUNUIORYXQTCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II) 、 碘甲烷 以 二氯甲烷 为溶剂， 生成 iodo(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)
  参考文献：
  名称：

  Preparation of platinum complexes containing a thioamide-based SCS pincer ligand and their light emitting properties

  摘要：

  Reaction of 1,3-bis(1-pyrrolidin othiocarbonyl) benzene with PtCl2(PhCN)(2) afforded a platinum complex with eta(3)-S,C,S type coordination. The molecular structure of the SCS-pincer platinum(II) complex was determined by X-ray analysis. Substitution of chloro ligand with anionic ligands such as iodo and acetylide was carried out. The complexes exhibit strong emission in a glassy frozen state as well as in the solid state. Light-emitting diodes based on the complexes displayed red electroluminescence. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.003
• 作为产物：
  描述：

  1,3-bis(1-pyrrolidinothiocarbonyl)benzene 在 CuI 、 Et₃N 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 生成 phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)
  参考文献：
  名称：

  Preparation of platinum complexes containing a thioamide-based SCS pincer ligand and their light emitting properties

  摘要：

  Reaction of 1,3-bis(1-pyrrolidin othiocarbonyl) benzene with PtCl2(PhCN)(2) afforded a platinum complex with eta(3)-S,C,S type coordination. The molecular structure of the SCS-pincer platinum(II) complex was determined by X-ray analysis. Substitution of chloro ligand with anionic ligands such as iodo and acetylide was carried out. The complexes exhibit strong emission in a glassy frozen state as well as in the solid state. Light-emitting diodes based on the complexes displayed red electroluminescence. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.003