(p-cymene)Ru(PPh2CH2CH2C6H5)Cl2 | 577969-99-4

• 英文名称: (p-cymene)Ru(PPh2CH2CH2C6H5)Cl2
• CAS: 577969-99-4
• 化学式: C₃₀H₃₃Cl₂PRu
• 分子量: 596.542
• InChiKey: CZROCKUZDYZIIQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (p-cymene)Ru(PPh2CH2CH2C6H5)Cl2 以 氯苯 为溶剂， 以62%的产率得到(η1:η6.-(2-phenyl-1-diphenylphosphinoethane))ruthenium(II) dichloride
  参考文献：
  名称：

  Synthesis, Characterization, and Thermal Stability of (η⁶:η¹-C₆H₅CH₂CH₂PR₂)Ru(CH₃)₂ (R = Cy, Ph, Et)

  摘要：

  Several new arene-phosphine ligands were synthesized and used to prepare the following series of tethered dialkylruthenium(II) complexes: (eta(6):eta(1)-C6H5CH2CH2PR2)Ru(CH3)(2), where R = Cy (1), Ph (2), Et (3). The structures of complexes 1 and 2 were determined by X-ray diffraction. While complexes 1 and 2 were found to be more thermally stable than analogous nontethered analogues, complex 3 was found to decompose at room temperature. In preliminary studies, the use of complexes 1 and 2 as catalyst precursors for the polymerization of ethylene was examined.

  DOI：

  10.1021/om0300070
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 苯乙基二苯基膦 以 苯 为溶剂， 以95%的产率得到(p-cymene)Ru(PPh2CH2CH2C6H5)Cl2
  参考文献：
  名称：

  Synthesis, Characterization, and Thermal Stability of (η⁶:η¹-C₆H₅CH₂CH₂PR₂)Ru(CH₃)₂ (R = Cy, Ph, Et)

  摘要：

  Several new arene-phosphine ligands were synthesized and used to prepare the following series of tethered dialkylruthenium(II) complexes: (eta(6):eta(1)-C6H5CH2CH2PR2)Ru(CH3)(2), where R = Cy (1), Ph (2), Et (3). The structures of complexes 1 and 2 were determined by X-ray diffraction. While complexes 1 and 2 were found to be more thermally stable than analogous nontethered analogues, complex 3 was found to decompose at room temperature. In preliminary studies, the use of complexes 1 and 2 as catalyst precursors for the polymerization of ethylene was examined.

  DOI：

  10.1021/om0300070