(E)-tetramethyl 2,2'-(1,4-phenylenebis(methylene))bis(2-((E)-4-acetoxy-2-methylbut-2-enyl)malonate) | 1311467-92-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (E)-tetramethyl 2,2'-(1,4-phenylenebis(methylene))bis(2-((E)-4-acetoxy-2-methylbut-2-enyl)malonate)
• CAS: 1311467-92-1
• 化学式: C₃₂H₄₂O₁₂
• 分子量: 618.678
• InChiKey: ZIBAZOLCOHLXPI-JFMUQQRKSA-N

反应信息

• 作为反应物：
  描述：

  (E)-tetramethyl 2,2'-(1,4-phenylenebis(methylene))bis(2-((E)-4-acetoxy-2-methylbut-2-enyl)malonate) 在 silver hexafluoroantimonate 、 三苯基膦氯金 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以65%的产率得到tetramethyl 4,8-dimethyl-4,8-divinyl-3,4,7,8-tetrahydroanthracene-2,2,6,6 (1H,5H)-tetracarboxylate
  参考文献：
  名称：

  Gold catalyzed carbocyclization of phenyl substituted allylic acetates to synthesize benzocycle derivatives

  摘要：

  An efficient and environmentally benign method was developed to synthesize the benzocycles from phenyl substituted allylic acetates through gold catalyzed Friedel-Crafts type carbocyclization reaction. Different substitution patterns were investigated, which gave a series of benzocyclohexane derivatives in moderate to excellent yields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.03.142