5,6-epoxy-2-phenyl-hexahydro-isoindole-1,3-dione | 75389-04-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 5,6-epoxy-2-phenyl-hexahydro-isoindole-1,3-dione
• 英文别名: 4-Phenyl-1a,2,2a,5a,6,6a-hexahydrooxireno[2,3-f]isoindole-3,5-dione
• CAS: 75389-04-7
• 化学式: C₁₄H₁₃NO₃
• 分子量: 243.262
• InChiKey: RWBOFYYFPWEKRT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  49.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-phenyl-3a,4,7,7a-tetrahydro-1H-isoindole-1,3(2H)-dione 在 过氧乙酸 作用下， 以 溶剂黄146 为溶剂， 生成 5,6-epoxy-2-phenyl-hexahydro-isoindole-1,3-dione
  参考文献：
  名称：

  Batog, A. E.; Savenko, T. V.; Batrak, T. A., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, p. 1860 - 1862

  摘要：

  DOI：

文献信息

• RESIN COMPOSITION AND MOLDED ARTICLE COMPRISING THE SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1903077A1

  公开（公告）日：2008-03-26

  A resin composition comprising a polylactic acid-based resin (A) and methacrylic resins (B), wherein the methacrylic resins having at least (a) a difference of 10°C or more in glass transition temperature or (b) a difference of 3% or more in syndiotacticity; it is preferred that at least one of the methacrylic resins (B) is a methacrylic resin having a weight average molecular weight of 50,000 to 450,000, a glass transition temperature of 110°C or higher and a syndiotacticity of 40% or more, and that the resin composition further contains a multilayer structure polymer formed as particles each consisting of a core layer and one or more shell layers covering it (C). A molded article made of said resin composition.

  一种树脂组合物，包括聚乳酸基树脂（A）和甲基丙烯酸树脂（B），其中甲基丙烯酸树脂至少(a)在玻璃化转变温度上相差 10°C 或更多，或(b)在联合活度上相差 3% 或更多；优选至少一种甲基丙烯酸树脂 (B) 是重量平均分子量为 50,000 至 450,000 的甲基丙烯酸树脂，玻璃化温度为 110°C 或更高，辛二酸度为 40% 或更高，并且该树脂组合物还包含一种多层结构聚合物，该聚合物形成为颗粒，每个颗粒由芯层和覆盖在芯层上的一层或多层壳层组成 (C)。由所述树脂组合物制成的模塑制品。
• RESIN COMPOSITION, METHOD FOR PRODUCING THE SAME AND MOLDED ARTICLE
  申请人：TEIJIN LIMITED

  公开号：EP2053091A1

  公开（公告）日：2009-04-29

  To provide a resin composition having high heat resistance with a high melting point and excellent melt stability and hydrolysis resistance, a molded article of the resin composition and a method of manufacturing the resin composition; the resin composition comprises an aromatic polyester (component A) having a butylene terephthalate skeleton as the main constituent unit and polylactic acid (component B) having a melting point of 190°C or higher.

  提供一种具有高熔点、高耐热性、优异的熔融稳定性和耐水解性的树脂组合物、一种由该树脂组合物制成的模塑制品以及一种制造该树脂组合物的方法；该树脂组合物由具有对苯二甲酸丁二醇酯骨架作为主要组成单元的芳香族聚酯（A 组分）和熔点为 190°C 或更高的聚乳酸（B 组分）组成。
• POLYLACTIC ACID COMPOSITION
  申请人：Teijin Limited

  公开号：EP2116576A1

  公开（公告）日：2009-11-11

  It is an object of the present invention to provide a polylactic acid composition having excellent crystallinity, wet heat stability and melt stability. It is another object of the present invention to provide a molded article which is obtained from the polylactic acid composition and excellent in appearance and color. The present invention is a composition and molded article thereof which comprises a polylactic acid (component A), a carbodiimide compound (component B) and a phosphoric acid ester metal salt (component C).

  本发明的一个目的是提供一种具有优异结晶度、湿热稳定性和熔融稳定性的聚乳酸组合物。本发明的另一个目的是提供一种由该聚乳酸组合物制成的模塑制品，其外观和色泽极佳。 本发明是一种由聚乳酸（A 组分）、碳化二亚胺化合物（B 组分）和磷酸酯金属盐（C 组分）组成的组合物及其成型品。
• AROMATIC POLYCARBONATE RESIN COMPOSITION
  申请人：Teijin Chemicals, Ltd.

  公开号：EP2213703A1

  公开（公告）日：2010-08-04

  The object of this invention is to provide a resin composition that contains a polymer obtained from biomass resources and constitutes molded articles excellent in heat resistance, mechanical properties and durable stability, this invention including a resin composition comprising (i) a resin component containing 95 to 5 % by weight of an aromatic polycarbonate (component A) and 5 to 95 % by weight of polylactic acid (component B), (ii) 0.001 to 10 parts by weight, per 100 parts by weight of the resin component, of a phosphoric ester metal salt (component C), and (iii) 0.01 to 5 parts by weight, per 100 parts by weight of the polylactic acid (component B), of a terminal blocker (component F), the stereo-complex crystal content (X) of the following expression (I) being 80 % or more, X%=ΔHb/ΔHa+ΔHbx100 wherein ΔHa and ΔHb are a melting enthalpy (ΔHa) of a crystal melting point that appears at lower than 190°C and a melting enthalpy (ΔHb) of a crystal melting point that appears at 190°C or higher but less than 250°C, respectively, in a temperature-elevation process by a differential scanning calorimeter (DSC), and molded articles thereof.

  本发明的目的是提供一种树脂组合物，该树脂组合物含有一种从生物质资源中获得的聚合物，并构成耐热性、机械性能和持久稳定性极佳的模塑制品，本发明包括一种树脂组合物，该树脂组合物包括 (i) 含有 95-5%（按重量计）芳香族聚碳酸酯（组分 A）和 5-95%（按重量 计）聚乳酸（组分 B）的树脂组分、 (ii) 以每 100 份树脂组分重量计，含 0.001 至 10 份磷酸酯金属盐（组分 C），和 (iii) 以每 100 份聚乳酸（组分 B）的重量计，0.01 至 5 份末端封端剂（组分 F）、 以下表达式（I）中立体络合物晶体含量（X）为 80%或以上，X%=ΔHb/ΔHa+ΔHbx100 其中，ΔHa 和 ΔHb 分别是在差示扫描量热仪 (DSC) 的升温过程中，出现在低于 190°C 的晶体熔点的熔化焓 (ΔHa)，以及出现在 190°C 或更高但低于 250°C 的晶体熔点的熔化焓 (ΔHb)。
• FILM
  申请人：Teijin Limited

  公开号：EP2189493A1

  公开（公告）日：2010-05-26

  A film made of a resin composition which comprises polylactic acid (component A) composed of poly(L-lactic acid) and poly(D-lactic acid) and acrylic resin (component B) and has a crystal melting peak at 190°C or higher when measured by a scanning differential calorimeter (DSC). The film has a small change in birefringence caused by external force, excellent dimensional stability at the time of heating and a small change in birefringence caused by heat stress.

  一种由树脂组合物制成的薄膜，该树脂组合物包括由聚(L-乳酸)和聚(D-乳酸)组成的聚乳酸（A 组分）和丙烯酸树脂（B 组分），用扫描微分量热仪（DSC）测量，其晶体熔点在 190°C 或更高。 该薄膜在外力作用下的双折射变化很小，加热时的尺寸稳定性极佳，热应力引起的双折射变化也很小。