dinitroacetaldehyde phenylhydrazone potassium salt | 138555-26-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dinitroacetaldehyde phenylhydrazone potassium salt
• CAS: 138555-26-7
• 化学式: C₈H₇N₄O₄*K
• 分子量: 262.266
• InChiKey: OLGNZCYPSYUKSP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1-anilino-2,2-dinitroethylene potassium salt 、 苯肼 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 以57%的产率得到dinitroacetaldehyde phenylhydrazone potassium salt
  参考文献：
  名称：

  gem-Dinitro compounds in organic synthesis. 1. Synthesis of functionally substituted polynitro compounds with the use of the universal synthon, ethyl dinitroacetate

  摘要：

  Ethyl nitroacetate (I) was used as a synthon in the preparation of dinitromethane, dinitroacetic acid, 2,2-dinitroethanol, fluorodinitromethane, 1,1,3,3-tetranitropropane, and some condensation products of Henry and Mannich reactions. A number of dinitroacetaldehyde derivatives were also prepared: its potassium salt, oxime, and hydrazone, dinitroacetaldehyde azine; and mixed azines with other acetaldehydes.

  DOI：

  10.1007/bf01172267