sodium salt of salicylidene-2-methyl-1-aminobenzene | 50360-14-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium salt of salicylidene-2-methyl-1-aminobenzene
• 英文别名: sodium salt of N-phenylsalicylideneimine；sodium salicylidenephenylaminate；Sodium;2-(phenyliminomethyl)phenolate
• CAS: 50360-14-0
• 化学式: C₁₃H₁₀NO*Na
• 分子量: 219.218
• InChiKey: HMCNWZHTXWMOOU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.49
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  sodium salt of salicylidene-2-methyl-1-aminobenzene 、 三正丙基氯化锡 以 乙醇 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  有机锡（IV）的席夫碱配合物。三烷基锡（IV）氯化物和醇盐与N取代的水杨叉亚胺的反应

  摘要：

  通过使三烷基锡氯化物或醇盐与相应的席夫碱反应，已经合成了十八种新的挥发性N-取代的水杨基亚氨基亚氨基三烷基锡衍生物。在红外和质子磁共振测量的基础上，对这些配合物中的锡提出了五种配位方案。

  DOI：

  10.1016/s0022-328x(00)92485-9
• 作为产物：
  描述：

  亚水杨基苯胺 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 以96%的产率得到sodium salt of salicylidene-2-methyl-1-aminobenzene
  参考文献：
  名称：

  Metal and Ligand-Substituent Effects in the Immortal Polymerization ofrac-Lactide with Li, Na, and K Phenoxo-imine Complexes

  摘要：

  A series of lithium, sodium, and potassium complexes with phenoxo-imine ligands M[(O-2-(RN=CH)-C6H4] [R = C6H5; 2-(BuC6H5)-Bu-t; 2,6-(Pr2C6H3)-Pr-i] and [O-2-(RN=CH)-4,6-(Bu2C6H4)-Bu-t] [R = C6H5; 2-(BuC6H5)-Bu-t; 2,6-(Pr2C6H3)-Pr-i] 1-3(a-f) have been synthesized. The molecular structures in the solid state of some of these complexes have been determined by X-ray diffraction. These compounds show different nuclearities and geometries around the metal center depending on the nature and the pocket of the ligand substituents. Of particular interest is the structure of compound 3e, being the first example of a potassium cubane complex obtained with this kind of ligand. The structural behavior in solution has also been studied by diffusion-ordered NMR spectroscopy (DOSY), showing a direct correlation between aggregation behavior and polymerization activity. Compounds 1-3(a-f) are extremely active catalysts in the ring-opening polymerization (ROP) of rac-lactide, achieving conversions of 100% in less than 1 min and heterorich-PLA that is modified by the metal atom and the ligand substituents. BnOH was used as co-initiator, and the presence of large amounts of the alcohol produces the immortal polymerization of rac-lactide in a more controlled process. Stoichiometric reactions involving the catalysts, BnOH, and lactide demonstrated an activated monomer mechanism for the polymerization of rac-lactide.

  DOI：

  10.1021/om501000b

文献信息

• Synthesis, molecular structures and norbornene addition polymerization activity of the neutral nickel catalysts supported by N-naphthyl-salicylaldiminato ligands
  作者：Wei-Hua Wang、Guo-Xin Jin

  DOI：10.1016/j.inoche.2004.11.025

  日期：2005.1

  Abstract A series of nickel Schiff-base complexes were synthesized by the reaction of Schiff-bases containing N-naphththyl group with trans-[Ni(PPh3)2(Ph)Cl] and they were characterized by EA, IR and NMR. When activated by methylaluminoxane, these complexes exhibit good catalytic activity for the addition polymerization of norbornene.

  摘要 通过含有N-萘基的席夫碱与反式-[Ni(PPh3)2(Ph)Cl]反应合成了一系列镍席夫碱配合物，并对其进行了电分析、红外光谱和核磁共振表征。当被甲基铝氧烷活化时，这些配合物对降冰片烯的加成聚合表现出良好的催化活性。
• Singh, P. P.; Srivastava, Beena, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1986, vol. 25, # 12, p. 1109 - 1113
  作者：Singh, P. P.、Srivastava, Beena

  DOI：——

  日期：——
• Dubey; Mishra, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2006, vol. 45, # 10, p. 2203 - 2208
  作者：Dubey、Mishra

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  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Comp.12, 1.4.1.1.1.3.2.3, page 8 - 10
  作者：

  DOI：——

  日期：——
• Jain, V. K.; Bohra, R.; Mehrotra, R. C., Australian Journal of Chemistry, 1980, vol. 33, # 12, p. 2749 - 2752
  作者：Jain, V. K.、Bohra, R.、Mehrotra, R. C.

  DOI：——

  日期：——