chlorodimethylarsenium trifluoromethanesulfonate | 141103-54-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: chlorodimethylarsenium trifluoromethanesulfonate
• CAS: 141103-54-0
• 化学式: CF₃O₃S*C₂H₆AsClN
• 分子量: 303.521
• InChiKey: LLGNDFSZQMTTSZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.37
• 重原子数：
  13.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  60.44
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  N,N-二甲基三甲基硅胺 、 chlorodimethylarsenium trifluoromethanesulfonate 以100%的产率得到bis(dimethylamino)arsenium trifluoromethanesulfonate
  参考文献：
  名称：

  Chlorodialkylaminoarsenium salts : synthesis and rirst arsenium reactivity examples

  摘要：

  Chlorodialkylaminoarsenium trifluoromethanesulfonates are obtained by reaction of dichlorodialkylaminoarsanes (R2NAsCl2) on silver trifluoromethanesulfonate (CF3SO3Ag). Their reactivity, (first example of arsenium one), with silylated reagents of the type Me3SiX leads either to neutral (X = CN) cyanodialkylaminochloroarsanes or to arsenium salts (X = NMe2) like bis(dialkylamino)arsenium trifluoromethanesulfonates.

  DOI：

  10.1016/s0040-4039(00)91599-5
• 作为产物：
  描述：

  Dimethylamino-dichlor-arsan 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以100%的产率得到chlorodimethylarsenium trifluoromethanesulfonate
  参考文献：
  名称：

  Chlorodialkylaminoarsenium salts : synthesis and rirst arsenium reactivity examples

  摘要：

  Chlorodialkylaminoarsenium trifluoromethanesulfonates are obtained by reaction of dichlorodialkylaminoarsanes (R2NAsCl2) on silver trifluoromethanesulfonate (CF3SO3Ag). Their reactivity, (first example of arsenium one), with silylated reagents of the type Me3SiX leads either to neutral (X = CN) cyanodialkylaminochloroarsanes or to arsenium salts (X = NMe2) like bis(dialkylamino)arsenium trifluoromethanesulfonates.

  DOI：

  10.1016/s0040-4039(00)91599-5