copper(I) triethylenetetramine perchlorate | 823180-65-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: copper(I) triethylenetetramine perchlorate
• CAS: 823180-65-0
• 化学式: C₆H₁₈CuN₄*ClO₄
• 分子量: 309.232
• InChiKey: MARYOZQUVPGJPL-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  copper(I) triethylenetetramine perchlorate 、 nickel(II)(1,3,5-triazapentanediene)(NHCHNCHNH) perchlorate 以 乙醇 、 水 为溶剂， 以60%的产率得到[copper(II) triethylenetetramine]2[nickel(II)bis(.kappa1N:κ2N-NHCHNCHNH)] perchlorate
  参考文献：
  名称：

  1,3,5‐Triazapentanediene, A Novel Tridentate Ligand that Bridges Two Metal Ions in a κ ¹ N :κ ² N Bridging Mode with C ₂ Symmetry

  摘要：

  AbstractThe new mononuclear complexes [Ni(Htap)2](ClO4)2 (1) and [Ni(tap)(Htap)]ClO4 (2) were synthesized by the reaction of nickel(II) perchlorate and 1,3,5‐triazine (Htap = 1,3,5‐triazapentanediene). In 1 and 2, neutral Htap and a monoanionic tap− coordinate in a square‐planar mode to the nickel(II) ions (low‐spin state) in a bidentate, chelating fashion. Using the central N of tap− of 2 as a donor atom, multinuclear complexes [{Cu(tren)}2{Ni(tap)2}](ClO4)4 (3) and [Ni(Htap)2]2[Ni{Ni(tap)(Htap)}2(NCS)4][Ni{Ni(tap)(Htap)}(NCS)5]2 (4) were synthesized. In both complexes, tap− binds two metal ions in a κ1N:κ2N bridging mode, with C2 symmetry along the Ni−Cu axis for 3 and Ni−Ni axis for 4. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

  DOI：

  10.1002/ejic.200400122