([Mn(N,N-bis(2-hydroxyethyl)glycinate)Cl]2*2(H2O))n | 194363-15-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: ([Mn(N,N-bis(2-hydroxyethyl)glycinate)Cl]2*2(H2O))n
• CAS: 194363-15-0
• 化学式: C₆H₁₂NO₄*Cl*H₂O*Mn
• 分子量: 270.572
• InChiKey: MWGJXFCSCRAWSS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -6.8
• 重原子数：
  14.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  115.33
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 N,N-二羟乙基甘氨酸 在 Me₄NOH 作用下， 以 甲醇 为溶剂， 以68%的产率得到([Mn(N,N-bis(2-hydroxyethyl)glycinate)Cl]2*2(H2O))n
  参考文献：
  名称：

  One-dimensional polymeric bicinate manganese complex

  摘要：

  The synthesis, X-ray structure and magnetochemical properties of the one-dimensional polymeric bicinate (bic(-)) manganese complex {[Mn(bic)Cl](2) . 2(H2O)}(n). Each mangenese ion has distorted octahedral coordination geometry. Bicine is a pentadentate ligand using one nitrogen, and four oxygen atoms to coordinate to the Mn-II ion. The two hydroxyl groups are not deprotonated and the carboxylate moiety of the bic(-) ligand ion is a bridge leading to a one-dimensional chain. The water molecules are not coordinated to the Mn-II ions, but are involved in hydrogen-bonding interactions with the chain. Only weak pairwise antiferromagnetic exchange interactions (J = -0.30 cm(-1)) are found within the chain complex due to the carboxylate bridges. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00073-9