Ni(3,3'-(3,6-dioxaoctane-1,8-diyldioxy)bis(2-hydroxybenzaldehyde)bis(O-methyloxime)(-2H)(2-))*H2O | 848724-74-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Ni(3,3'-(3,6-dioxaoctane-1,8-diyldioxy)bis(2-hydroxybenzaldehyde)bis(O-methyloxime)(-2H)(2-))*H2O
• CAS: 848724-74-3
• 化学式: C₂₂H₂₆N₂NiO₈*H₂O
• 分子量: 523.162
• InChiKey: GYAUVQHATKVFJZ-BIYUQBHSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (Ba(H2O)CF3SO3Ni(H2O)(3,3'-(3,6-dioxaoctane-1,8-diyldioxy)bis(2-hydroxybenzaldehyde)bis(O-methyloxime)(-2H)(2-)))2(CF3SO3)2*4H2O 、 水 在 guanidinium sulfate 作用下， 以 氯仿 、 水 为溶剂， 以28%的产率得到Ni(3,3'-(3,6-dioxaoctane-1,8-diyldioxy)bis(2-hydroxybenzaldehyde)bis(O-methyloxime)(-2H)(2-))*H2O
  参考文献：
  名称：

  Magnetic coupling switch by means of host–guest chemistry in a polyether side-arm

  摘要：

  Complexation from the polyether ligand (LH2), Ni(CH3CO2)(2), and Ba(CF3SO3)(2) gave BaNiL (.) 2CF(3)SO(3), which showed ferromagnetic coupling ascribable to the dimer structure determined by means of X-ray crystallographic analysis. After removal of Ba2+ by treatment with guanidinium sulfate, NiL was isolated as an empty host, which did not show ferromagnetic coupling. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.09.011