| 1219683-89-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1219683-89-2
• 化学式: C₁₇₄H₂₅₁BrO₃₄
• 分子量: 2966.79
• InChiKey: NDQWGUSEFSZHLX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Tert-butyl 2-[3-[[3-[4-[[3-[[4-[3,5-bis[[3-decoxy-5-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethoxy]phenyl]methoxy]phenyl]-3-decoxy-5-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethoxy]phenyl]methoxy]-5-[4-(hydroxymethyl)-2-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethoxy]-6-pent-4-ynoxyphenyl]phenoxy]methyl]-2-decoxy-6-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethoxy]phenyl]-5-[[3-decoxy-5-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethoxy]phenyl]methoxy]phenoxy]methyl]-5-decoxyphenoxy]acetate 在 四溴化碳 、 三苯基膦 作用下， 以90%的产率得到
  参考文献：
  名称：

  Site-Specific Installation and Study of Electroactive Units in Every Layer of Dendrons

  摘要：

  Whereas encapsulation of functional groups at the core of dendrimers is well-understood, very little is known about their intermediate layers or even the periphery. Here we report oil a systematic investigation of every layer of dendrimers by incorporating a single ferrocene unit in well-defined locations in dendrons. Site-specific incorporation of the ferrocene unit was achieved by utilizing the dendrimer sequencing methodology. We show here that the redox potential values of ferrocene at intermediate layers were remarkably different from those at the core and the periphery. Although redox potential values were location-dependent, no significant change in the rate of heterogeneous electron transfer (k(0)) was observed with respect to locations. This was attributed to the possibility that free rotation of dendrimer nullifies the distance between the electrode and ferrocene unit. Finally, we also show that no Faradaic current was observed for the amphiphilic assemblies of these dendrons, whereas the same dendron did exhibit significant Faradaic current in nonassembling solvent environments.

  DOI：

  10.1021/jo902109u