trans-{Pd(2,6-bis(acetylacetoxymethyl)pyridine)2Cl2} | 136899-90-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 酮酸及其衍生物
• 英文名称: trans-{Pd(2,6-bis(acetylacetoxymethyl)pyridine)2Cl2}
• CAS: 136899-90-6
• 化学式: C₃₀H₃₄Cl₂N₂O₁₂Pd
• 分子量: 791.932
• InChiKey: RSKYCDNHGGJDPX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-{Pd(2,6-bis(acetylacetoxymethyl)pyridine)2Cl2} 在 吡啶 作用下， 以 吡啶 为溶剂， 生成 trans-{Pd(2,6-bis(acetylacetoxymethyl)pyridine)(pyridine)Cl2}
  参考文献：
  名称：

  Trinuclear complexation of 2,6-bis(acetylacetoxymethyl)pyridine with Pd(II) and Cu(II) ions

  摘要：

  Treatment of [PdCl2(PhCN)2] with 2,6-disubstituted pyridines (L) gave a new series of trans-[PdCl2L2] complexes. beta-Ketoester substituents in the ligands were found to form O-O chelate compounds with a Cu(II)ion. The Pd(II) complex of 2,6-bis(acetylacetoxymethyl)pyridine reacted with copper(II) acetate in dioxane to yield a (Cu(II), Pd(II), Cu(II)) trinuclear complex, which incorporated dioxane in the crystals. NMR, IR and reflectance spectra of the products were examined.

  DOI：

  10.1016/s0020-1693(00)83001-7
• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 2,6-bis(acetylacetoxymethyl)pyridine 以 苯 为溶剂， 以75%的产率得到trans-{Pd(2,6-bis(acetylacetoxymethyl)pyridine)2Cl2}
  参考文献：
  名称：

  Trinuclear complexation of 2,6-bis(acetylacetoxymethyl)pyridine with Pd(II) and Cu(II) ions

  摘要：

  Treatment of [PdCl2(PhCN)2] with 2,6-disubstituted pyridines (L) gave a new series of trans-[PdCl2L2] complexes. beta-Ketoester substituents in the ligands were found to form O-O chelate compounds with a Cu(II)ion. The Pd(II) complex of 2,6-bis(acetylacetoxymethyl)pyridine reacted with copper(II) acetate in dioxane to yield a (Cu(II), Pd(II), Cu(II)) trinuclear complex, which incorporated dioxane in the crystals. NMR, IR and reflectance spectra of the products were examined.

  DOI：

  10.1016/s0020-1693(00)83001-7