[Dy(N-(2-pyridylmethyl)iminodiacetate)(NO3)(H2O)] | 1004794-94-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Dy(N-(2-pyridylmethyl)iminodiacetate)(NO3)(H2O)]
• 英文别名: [Dy(pmida)(NO3)(H2O)]
• CAS: 1004794-94-8
• 化学式: C₁₀H₁₀N₂O₄*Dy*H₂O*NO₃
• 分子量: 464.721
• InChiKey: PNNVQWMXFVVEHQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.68
• 重原子数：
  22.0
• 可旋转键数：
  6.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  194.09
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  [Dy(N-(2-pyridylmethyl)iminodiacetate)(NO3)(H2O)] 以 neat (no solvent, solid phase) 为溶剂， 生成 dysprosium((III) oxide
  参考文献：
  名称：

  2D network coordination polymers of lanthanide with N-(2-pyridylmethyl)iminodiacetic acid: Hydrothermal syntheses, crystal structures and luminescent properties

  摘要：

  Six lanthanide two-dimensional network coordination polymers with the general formula of [Ln(pmida)(NO3)(H2O)](n), where Ln = La (1), Nd (2), Sm (3), Gd (4), Dy (5), Er (6) and pmida(2-) = N-(2-pyridylmethyl)iminodiacetate, have been synthesized by hydrothermal process and characterized by elemental analysis, Infrared spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. All crystals are isostructural and crystallize in the monoclinic space group P2(1/a). The lanthanide(III) ion is nine-coordinated in a geometry of distorted tricapped trigonal prism by two N atoms and two O atoms from one pmida(2-) ligand, two bridging carboxylate O atoms from other two pmida(2-) ligands, two O atoms of a bidentate chelating nitrate and a O atom of a coordinated water molecule. The luminescent properties of [Sm(pmida)(NO3)(H2O)](n) (3) and [Dy(pmida)(NO3)(H2O)](n) (5) were investigated. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.07.005
• 作为产物：
  描述：

  dysprosium(III) nitrate hexahydrate 、 水 、 N-(2-pyridylmethyl)iminodiacetic acid 在 Et₃N 作用下， 以 水 为溶剂， 生成 [Dy(N-(2-pyridylmethyl)iminodiacetate)(NO3)(H2O)]
  参考文献：
  名称：

  2D network coordination polymers of lanthanide with N-(2-pyridylmethyl)iminodiacetic acid: Hydrothermal syntheses, crystal structures and luminescent properties

  摘要：

  Six lanthanide two-dimensional network coordination polymers with the general formula of [Ln(pmida)(NO3)(H2O)](n), where Ln = La (1), Nd (2), Sm (3), Gd (4), Dy (5), Er (6) and pmida(2-) = N-(2-pyridylmethyl)iminodiacetate, have been synthesized by hydrothermal process and characterized by elemental analysis, Infrared spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. All crystals are isostructural and crystallize in the monoclinic space group P2(1/a). The lanthanide(III) ion is nine-coordinated in a geometry of distorted tricapped trigonal prism by two N atoms and two O atoms from one pmida(2-) ligand, two bridging carboxylate O atoms from other two pmida(2-) ligands, two O atoms of a bidentate chelating nitrate and a O atom of a coordinated water molecule. The luminescent properties of [Sm(pmida)(NO3)(H2O)](n) (3) and [Dy(pmida)(NO3)(H2O)](n) (5) were investigated. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.07.005