4,5-dimethoxy-2-nitrobenzyl (2,6-bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-4-(hydroxymethyl)phenyl)carbamate | 1590443-36-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,5-dimethoxy-2-nitrobenzyl (2,6-bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-4-(hydroxymethyl)phenyl)carbamate
• CAS: 1590443-36-9
• 化学式: C₃₅H₅₄N₂O₉Si₂
• 分子量: 702.993
• InChiKey: UKYNDQCYPVZZAD-WXUKJITCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.92
• 重原子数：
  48.0
• 可旋转键数：
  15.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.51
• 拓扑面积：
  138.62
• 氢给体数：
  2.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  4,5-dimethoxy-2-nitrobenzyl (2,6-bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-4-(hydroxymethyl)phenyl)carbamate 在 盐酸 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以86%的产率得到4,5-dimethoxy-2-nitrobenzyl (4-(hydroxymethyl)-2,6-bis((E)-3-hydroxyprop-1-en-1-yl)phenyl)carbamate
  参考文献：
  名称：

  Production of three radical cations from a single photon using a photo acid generator

  摘要：

  Efficient generation of the organic radicals is a fundamental technology for preparing the spintronic materials. In this Letter, we present the chemical reaction of the three radical generation from a single photon. A photo acid generator which can release the multiple acid molecules via the automatic amplification mechanism was synthesized. The synthesized acid generator immediately released methanesulfonic acid by UV irradiation. Due to the amplification system, a maximum of three acid molecules can be produced from the single acid generator. In addition, the release of acid is induced by UV irradiation and automatically proceeds until the release of three acid molecules is finished. Finally, by employing the acid-catalyzed radical generation of tetrathiafulvalene, we also demonstrate the efficient radical generation triggered by UV irradiation in the polymer film. (c) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.092
• 作为产物：
  描述：

  苯佐卡因 在 potassium phosphate 、 碘 、 palladium diacetate 、 二异丁基氢化铝 、 碳酸氢钠 、 silver sulfate 、 三苯基膦 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 乙醇 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 6.83h， 生成 4,5-dimethoxy-2-nitrobenzyl (2,6-bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-4-(hydroxymethyl)phenyl)carbamate
  参考文献：
  名称：

  Production of three radical cations from a single photon using a photo acid generator

  摘要：

  Efficient generation of the organic radicals is a fundamental technology for preparing the spintronic materials. In this Letter, we present the chemical reaction of the three radical generation from a single photon. A photo acid generator which can release the multiple acid molecules via the automatic amplification mechanism was synthesized. The synthesized acid generator immediately released methanesulfonic acid by UV irradiation. Due to the amplification system, a maximum of three acid molecules can be produced from the single acid generator. In addition, the release of acid is induced by UV irradiation and automatically proceeds until the release of three acid molecules is finished. Finally, by employing the acid-catalyzed radical generation of tetrathiafulvalene, we also demonstrate the efficient radical generation triggered by UV irradiation in the polymer film. (c) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.092