[Zn(2,2'-bipyridine)(benzene-1,4-dicarboxylate)(H2O)] | 1140970-03-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Zn(2,2'-bipyridine)(benzene-1,4-dicarboxylate)(H2O)]
• CAS: 1140970-03-1
• 化学式: C₈H₄O₄*C₁₀H₈N₂*H₂O*Zn
• 分子量: 403.71
• InChiKey: DDYONEUENACUOV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  对苯二甲酸 、 Zn(II)(2,2'-bipyridyl)(NO3)2*H2O 在 aq. HNO₃ 、 triethylamine 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 以77%的产率得到[Zn(2,2'-bipyridine)(benzene-1,4-dicarboxylate)(H2O)]
  参考文献：
  名称：

  Metal–organic frameworks (MOFs) constructed from ZnII/CdII-2,2′-bipyridines and polycarboxylic acids: Synthesis, characterization and microstructural studies

  摘要：

  Metal-organic frameworks with the compositions [Zn(bpy)(bdc)(H2O)](n) 1, [Zn(bpy)(btec)(1/2)(H2O)](n) 2, [Cd(bpy)(bdc)(H2O)](n) 3 and [Cd(bpy)(btec)(1/2)(H2O)](n) 4 (H(2)bdc = 1,4-benzenedicarboxylic acid = terephthalic acid, H(4)btec = 1,2.4,5-benzenetetracarboxylic acid and bpy = 2,2'-bipyridine) have been synthesized and characterized using spectroscopic and single-crystal X-ray diffraction techniques. In these complexes, Zn-II/Cd-II-2,2'-bipyridine units and carboxylate anions exists as nodes and spacers respectively. An infinite 1D zig-zag chain structure is observed for both complexes I and 3, whereas complexes 2 and 4 display a 3D supramolecular architecture. The complexes are found to be photoluminescent, porous and show significant thermal stability. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.11.059