2,9,16,23-tetrakis(4-methylcoumarine-7-thio)phthalocyaninatocobalt(II) | 1051388-15-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• 英文名称: 2,9,16,23-tetrakis(4-methylcoumarine-7-thio)phthalocyaninatocobalt(II)
• CAS: 1051388-15-8
• 化学式: C₇₂H₄₀CoN₈O₈S₄
• 分子量: 1332.42
• InChiKey: PLZMLLRKEBRUFT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  溴己烷 、 2,9,16,23-tetrakis(4-methylcoumarine-7-thio)phthalocyaninatocobalt(II) 在 sodium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 以41%的产率得到2,9,16,23-tetrakis[3-hexyloxy-4-((E)-1-hydroxycarbonylprop-1-ene-2-yl)phenylthio]phthalocyaninatocobalt(II)
  参考文献：
  名称：

  Synthesis and electrochemistry of tetrakis(7-coumarinthio-4-methyl)-phthalocyanines, and preparation of their cinnamic acid and sodium cinnamate derivatives

  摘要：

  Novel water soluble free-base, Zn(II) and Co(II) metallo phthalocyanines with four cinnamic acid moieties were prepared from the corresponding tetrakis(7-coumarinthio-4-methyl)-phthalocyanine by the lactone ring opening reaction. The new compounds were purified and characterized by elemental analysis, H-1 NMR, Maldi-TOF, FT-IR and UV-Vis spectral data. Cyclic and differential pulse voltammetry and in situ spectroelectrochemistry of the 2,9,16,23-tetrakis(7-coumarinthio-4-methyl) substituted free-base 1a, Zn(II) 1b and Co(II) 1c phthalocyanines, employed as the starting compounds have been studied. This allowed us not only to identify metal- and phthalocyanine ring-based redox processes of the complexes, but also the effect of aggregation on these processes. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.09.021