1-(4-chlorophenyl)-2-(4-chlorobenzoyl)-3a,6a-diazapentalene | 98979-17-0

• 英文名称: 1-(4-chlorophenyl)-2-(4-chlorobenzoyl)-3a,6a-diazapentalene
• 英文别名: 1-<4-Chlor-benzoyl>-2-<4-chlor-phenyl>-pyrazolo<1.2-a>pyrazol；1-(p-Chlorbenzoyl)-2-(p-chlorphenyl)-pyrazolo<1,2-a>pyrazol；1-(4-chloro-benzoyl)-2-(4-chloro-phenyl)-pyrazolo[1,2-a]pyrazolyliumide
• CAS: 98979-17-0
• 化学式: C₁₉H₁₂Cl₂N₂O
• 分子量: 355.223
• InChiKey: VLNTVTKWTCYRQS-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  丁炔二酸二甲酯 、 1-(4-chlorophenyl)-2-(4-chlorobenzoyl)-3a,6a-diazapentalene 以 苯 为溶剂， 以54%的产率得到tetramethyl 3-(p-chlorobenzoyl)-10-ethynyl-2-(p-chlorophenyl)-4,10-diazabicyclo[5.2.1]dec-1,3,5,8-tetraene-8,9,10(1',2')-tetracarboxylate
  参考文献：
  名称：

  A Facile Formation of anti-Bredt’s Compounds from the Reaction of 1-Aroyl-2-aryl-3a,6a-diazapentalenes with Acetylenedicarboxylates

  摘要：

  DOI：

  10.3987/com-04-s(p)48

文献信息

• Unusual formation and X-ray crystal structure of stable anti-Bredt compounds by reaction of 3a,6a-diazapentalenes with dimethyl acetylenedicarboxylate
  作者：Kiyoshi Matsumoto、Hirokazu Iida、Hideki Katsura、Takahisa Machiguchi、Hidehiro Uekusa、Yuji Ohashi

  DOI：10.1039/p19960002333

  日期：——

  The reaction of 1-aroyl-2-aryl-3a,6a-diazapentalenes with dimethyl acetylenedicarboxylate affords, in an unusual fashion, stable anti-Bredt compounds possessing a 4,10-diazabicyclo[5.2.1]deca-1,3,5,8-tetraene skeleton, the structure of which is confirmed by X-ray crystal structure analysis as well as by 1H and 13C NMR spectroscopy.

  1-芳酰基-2-芳基-3a，6a-二氮杂戊烯与乙炔二甲酸二甲酯的反应以异常的方式提供了稳定的抗-Bredt化合物，其具有4,10-二氮杂双环[5.2.1] deca-1,3,5 ，8-四烯骨架，其结构通过X射线晶体结构分析以及1 H和13 C NMR光谱法确认。