Os(2,2'-bipyridine)2(trifluoromethanesulfonate)2 | 248955-02-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Os(2,2'-bipyridine)2(trifluoromethanesulfonate)2
• 英文别名: Os(bpy)2(OTf)2
• CAS: 248955-02-4
• 化学式: C₂₂H₁₆F₆N₄O₆OsS₂
• 分子量: 800.715
• InChiKey: WYRHYONIRKGBRN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 Os(2,2'-bipyridine)2(trifluoromethanesulfonate)2 、 2-(4-乙氧基羰基喹啉-2-基)喹啉-4-羧酸乙酯 以 丙酮 为溶剂， 以14%的产率得到[Os(bpy)2(4,4'-bis(ethoxycarbonyl)-2,2'-biquinoline)](PF6)2
  参考文献：
  名称：

  Toward Exceeding the Shockley−Queisser Limit:  Photoinduced Interfacial Charge Transfer Processes that Store Energy in Excess of the Equilibrated Excited State

  摘要：

  Nanocrystalline (anatase), mesoporous TiO2 thin films were functionalized with [Ru(bpy)(2)(deebq)](PF6)(2), [Ru(bq)(2)(deeb)](PF6)(2), [Ru(deebq)(2)(bpy)](PF6)(2), [Ru(bpy)(deebq)(NCS)(2)], or [Os(bpy)(2)(deebq)](PF6)(2), where bpy is 2,2'-bipyridine, bq is 2,2'-biquinoline, and deeb and deebq are 4,4'-diethylester derivatives. These compounds bind to the nanocrystalline TiO2 films in their carboxylate forms with limiting surface coverages of 8 (+/- 2) x 10(-8) mol/cm(2). Electrochemical measurements show that the first reduction of these compounds (-0.70 V vs SCE) occurs prior to TiO2 reduction. Steady state illumination in the presence of the sacrificial electron donor triethylamine leads to the appearance of the reduced sensitizer. The thermally equilibrated metal-to-ligand charge-transfer excited state and the reduced form of these compounds do not inject electrons into TiO2. Nanosecond transient absorption measurements demonstrate the formation of an extremely long-lived charge separated state based on equal concentrations of the reduced and oxidized compounds. The results are consistent with a mechanism of ultrafast excited-state injection into TiO2 followed by interfacial electron transfer to a ground-state compound. The quantum yield for this process was found to increase with excitation energy, a behavior attributed to stronger overlap between the excited sensitizer and the semiconductor acceptor states. For example, the quantum yields for [Os(bpy)(2)(dcbq)]/TiO2 were phi(417 nm) = 0.18 +/- 0.02, phi(532.5 nm) = 0.08 +/- 0.02, and phi(683 nm) = 0.05 +/- 0.01. Electron transfer to yield ground-state products occurs by lateral intermolecular charge transfer. The driving force for charge recombination was in excess of that stored in the photoluminescent excited state. Chronoabsorption measurements indicate that ligand-based intermolecular electron transfer was an order of magnitude faster than metal-centered intermolecular hole transfer. Charge recombination was quantified with the Kohlrausch-Williams-Watts model.

  DOI：

  10.1021/ja060470e
• 作为产物：
  描述：

  2,2'-联吡啶 在 LiCl 、 triethylamine 作用下， 以 N,N-二甲基甲酰胺 、 邻二氯苯 为溶剂， 生成 Os(2,2'-bipyridine)2(trifluoromethanesulfonate)2
  参考文献：
  名称：

  Toward Exceeding the Shockley−Queisser Limit:  Photoinduced Interfacial Charge Transfer Processes that Store Energy in Excess of the Equilibrated Excited State

  摘要：

  Nanocrystalline (anatase), mesoporous TiO2 thin films were functionalized with [Ru(bpy)(2)(deebq)](PF6)(2), [Ru(bq)(2)(deeb)](PF6)(2), [Ru(deebq)(2)(bpy)](PF6)(2), [Ru(bpy)(deebq)(NCS)(2)], or [Os(bpy)(2)(deebq)](PF6)(2), where bpy is 2,2'-bipyridine, bq is 2,2'-biquinoline, and deeb and deebq are 4,4'-diethylester derivatives. These compounds bind to the nanocrystalline TiO2 films in their carboxylate forms with limiting surface coverages of 8 (+/- 2) x 10(-8) mol/cm(2). Electrochemical measurements show that the first reduction of these compounds (-0.70 V vs SCE) occurs prior to TiO2 reduction. Steady state illumination in the presence of the sacrificial electron donor triethylamine leads to the appearance of the reduced sensitizer. The thermally equilibrated metal-to-ligand charge-transfer excited state and the reduced form of these compounds do not inject electrons into TiO2. Nanosecond transient absorption measurements demonstrate the formation of an extremely long-lived charge separated state based on equal concentrations of the reduced and oxidized compounds. The results are consistent with a mechanism of ultrafast excited-state injection into TiO2 followed by interfacial electron transfer to a ground-state compound. The quantum yield for this process was found to increase with excitation energy, a behavior attributed to stronger overlap between the excited sensitizer and the semiconductor acceptor states. For example, the quantum yields for [Os(bpy)(2)(dcbq)]/TiO2 were phi(417 nm) = 0.18 +/- 0.02, phi(532.5 nm) = 0.08 +/- 0.02, and phi(683 nm) = 0.05 +/- 0.01. Electron transfer to yield ground-state products occurs by lateral intermolecular charge transfer. The driving force for charge recombination was in excess of that stored in the photoluminescent excited state. Chronoabsorption measurements indicate that ligand-based intermolecular electron transfer was an order of magnitude faster than metal-centered intermolecular hole transfer. Charge recombination was quantified with the Kohlrausch-Williams-Watts model.

  DOI：

  10.1021/ja060470e