| 124464-32-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 124464-32-0
• 化学式: C₅₄H₃₃F₁₂P₂RuS₃
• 分子量: 1169.05
• InChiKey: NSRVOZJANIEMIO-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  [tris(triphenylphosphine) ruthenium(III) trichloride] 、 Pb(p-SC6HF4)2 以 丙酮 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  RuX = C (X  F or H) interactions in complex compounds. Preparation and crystal structures of [) (SC6F5)2(PMe2Ph)2] and [-2)(C6H5)22]

  摘要：

  The diamagnetic complex [Ru(SR)2(PPh3)2] and the paramagnetic compounds [Ru(SR)3(PR′3)2] (R = C6F5, C6F4H, C6FH4, or C6H5; PR′3 = PPh3, PMe2Ph or PEt2Ph) have been prepared by treatment of [RuCl2(PPh3)3] or [RuCl3(PR′3)3]. respectively, with [Pb(SR)2] in acetone or tetrahydrofuran. An X-ray diFfraction study on [-2)(C6H5)22] has revealed a pseudo-octahedral structure, apparently with two CHRu interactions

  DOI：

  10.1016/0022-328x(89)85432-4