| 113821-99-1

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• CAS: 113821-99-1
• 化学式: C₁₀H₂₃CuN₅O₂
• 分子量: 308.871
• InChiKey: QPFGFLINMZJSND-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 叔丁醇 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Pulse radiolysis of mono- and binuclear copper(II) macrocyclic complexes

  摘要：

  Pulse radiolytic reduction of a series of nitro-substituted tetraaza copper(II) complexes with the aquated electron (e(aq)) results in formation of nitro radical anions. By contrast, reaction of pendent nitro dithia-diaza copper(II) analogues with e(aq) achieves exclusive reduction of the metal centre. Oxidation of all tetraaza copper(II) complexes with the hydroxyl radical (OH) resulted in formation of stable copper(III) complexes, whereas no metal-centred oxidation was observed for the corresponding Cu(II)N2S2 complexes. The variation in reactivity, effectively evidence for selectivity in reduction with e(aq) or oxidation with OH, was attributed to the shift in the Cu(II/I) half-wave potentials going from a tetraaza to a dithia-diaza donor set.

  DOI：

  10.1016/s0277-5387(00)81271-1