(3S,5R,6R,8S,9S,10R,12R,13R,14S,17R)-10,13-Dimethyl-17-((R)-1,4,5-trimethyl-hexyl)-hexadecahydro-cyclopenta[a]phenanthrene-3,5,6,12-tetraol | 57637-30-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: (3S,5R,6R,8S,9S,10R,12R,13R,14S,17R)-10,13-Dimethyl-17-((R)-1,4,5-trimethyl-hexyl)-hexadecahydro-cyclopenta[a]phenanthrene-3,5,6,12-tetraol
• CAS: 57637-30-6
• 化学式: C₂₈H₅₀O₄
• 分子量: 450.703
• InChiKey: LAJMFQRDZBINHC-ADLXIRFKSA-N

反应信息

• 作为反应物：
  描述：

  三甲基氯硅烷 、 (3S,5R,6R,8S,9S,10R,12R,13R,14S,17R)-10,13-Dimethyl-17-((R)-1,4,5-trimethyl-hexyl)-hexadecahydro-cyclopenta[a]phenanthrene-3,5,6,12-tetraol 在 N,O-双三甲硅基乙酰胺 作用下， 以 吡啶 为溶剂， 生成 (3S,5R,6R,8S,9S,10R,12R,13R,14S,17R)-10,13-Dimethyl-17-((R)-1,4,5-trimethyl-hexyl)-3,6,12-tris-trimethylsilanyloxy-hexadecahydro-cyclopenta[a]phenanthren-5-ol
  参考文献：
  名称：

  24ξ-Methylcholestane-3β,5α,6β,12β,25-pentol 25-monoacetate, a novel polyoxygenated marine sterol

  摘要：

  24xi--Methylcholestane-3beta, 5alpha, 6beta, 12beta, 25-pentol 25-monoacetate has been isolated from an Alyconarian and its structure was established in part through extensive high resolution mass spectral and nmr studies and partly through the nonidentity of one of its degradation products with 24xi-methylcholestane-3beta, 5alpha, 6beta, 12alpha-tetrol synthesized from deoxycholic acid.

  DOI：

  10.1016/0039-128x(75)90009-4
• 作为产物：
  描述：

  Acetic acid (R)-1,1,2-trimethyl-5-((3S,5R,6R,8S,9S,10R,12R,13R,14S,17R)-3,5,6,12-tetrahydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-yl)-hexyl ester 在 platinum(IV) oxide N,O-双三甲硅基乙酰胺 、 氢气 、 溶剂黄146 作用下， 以 吡啶 为溶剂， 生成 (3S,5R,6R,8S,9S,10R,12R,13R,14S,17R)-10,13-Dimethyl-17-((R)-1,4,5-trimethyl-hexyl)-hexadecahydro-cyclopenta[a]phenanthrene-3,5,6,12-tetraol
  参考文献：
  名称：

  24ξ-Methylcholestane-3β,5α,6β,12β,25-pentol 25-monoacetate, a novel polyoxygenated marine sterol

  摘要：

  24xi--Methylcholestane-3beta, 5alpha, 6beta, 12beta, 25-pentol 25-monoacetate has been isolated from an Alyconarian and its structure was established in part through extensive high resolution mass spectral and nmr studies and partly through the nonidentity of one of its degradation products with 24xi-methylcholestane-3beta, 5alpha, 6beta, 12alpha-tetrol synthesized from deoxycholic acid.

  DOI：

  10.1016/0039-128x(75)90009-4