[Cd(quinolinic acid(-2H))] | 887626-47-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cd(quinolinic acid(-2H))]
• 英文别名: [Cd(2,3-pyridinecarboxylate)]
• CAS: 887626-47-3
• 化学式: C₇H₃NO₄*Cd
• 分子量: 277.515
• InChiKey: MQJJOIAZHIYNAZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.19
• 重原子数：
  13.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  93.15
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  cadmium(II) acetate dihydrate 、 2,3-吡啶二甲酸 以 水 为溶剂， 以72%的产率得到[Cd(quinolinic acid(-2H))]
  参考文献：
  名称：

  Syntheses, structures, and photoluminescent properties of four d10 metal-quinolinato coordination polymers with similar rod-like SBUs

  摘要：

  Four M-II quinolinato complexes, [Zn-2(quin)(2)(H2O)(3)](n) (1), [Zn(quin)(H2O)(2)](n) (2), [Zn(quin)(H2O)](n), (3) and [Cd(quin)](n) (4) (H(2)quin = 2,3-pyridinedicarboxylic acid or quinolinic acid), have been hydrothermally synthesized and structurally characterized. Xray diffraction analyses reveal that all of these four complexes are constructed from similar rod-like SBUs, [M(quin)](n), (M = Zn or Cd). Complexes I and 2 have similar I-D box-like chains but different packing structures; complex 3 has a 2-D grid-like network and complex 4 has an unusual 2-D bilayer structure. Due to the different structural features, these complexes exhibit different photoluminescent emissions: complex 1 at 439 nm (lambda(ex) = 345 nm),complex 2 at 428 nm (lambda(ex) = 360 nm), complex 3 at 508 nm (lambda(ex) = 304 nm) and complex 4 at 500 nm (lambda(ex) = 324 nm). (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.02.018