dichlorotris(3-methylpyridazine)(triphenylphosphine)ruthenium | 819051-83-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dichlorotris(3-methylpyridazine)(triphenylphosphine)ruthenium
• 英文别名: dichlororuthenium;3-methylpyridazine;triphenylphosphane
• CAS: 819051-83-7
• 化学式: C₃₃H₃₃Cl₂N₆PRu
• 分子量: 716.615
• InChiKey: DZWCRHVQDDRNNH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-甲基哒嗪 、 tris(triphenylphosphine)ruthenium(II) chloride 以 四氢呋喃 为溶剂， 以75%的产率得到dichlorotris(3-methylpyridazine)(triphenylphosphine)ruthenium
  参考文献：
  名称：

  Incorporation of polybasic aromatic amines into ruthenium(II) chloro complexes

  摘要：

  The reactions of RuCl2[P(C6H5)(3)](3) with excesses of various aromatic amines led to six coordinate, pseudo-octahedral complexes. Thus, three equivalents of pyridazine or 3-methylpyridazine could be incorporated, or two equivalents of pyrazole or phthalazine, all as monodentate ligands. Reaction with 1,8-naphthyridine led to the incorporation of one bidentate ligand. X-ray structural data were obtained for the pyridazine, phthalazine and 1,8-naphthyridine complexes. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.05.016