3-methoxyphenylphosphine | 473809-25-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-methoxyphenylphosphine
• 英文别名: (3-Methoxyphenyl)phosphane
• CAS: 473809-25-5
• 化学式: C₇H₉OP
• 分子量: 140.122
• InChiKey: QFNNMPZGMHATPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Novel phosphine compound, transition metal complex containing the same phosphine compound as ligand and asymmetric synthesis catalyst containing the complex
  申请人：——

  公开号：US20030144139A1

  公开（公告）日：2003-07-31

  A phosphine compound of formula (1) 1 and a phosphine compound of formula (2) 2 a transition metal complex having the phosphine compound as a ligand and a catalyst for asymmetric hydrogenation including the transition metal complex.

  一种化学式为(1)的膦化合物和一种化学式为(2)的膦化合物，其中所述膦化合物作为配体，形成一种过渡金属配合物，并且所述过渡金属配合物是一种不对称氢化反应的催化剂。
• Process for the preparation of glycol aldehyde
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0096905A1

  公开（公告）日：1983-12-28

  Process for the preparation of glycol aldehyde which comprises reacting formaldehyde with hydrogen and carbon monoxide in the presence of a catalyst system derived from a rhodium-containing catalyst precursor and/or a cobalt-containing catalyst precursor and an acid having a pKa ≥ 3.5 and a promoter XR3, X representing P, As or Sb and each R representing a (dis)similar substituted or unsubstituted hydrocarbyl group; at least one R representing an aryl group containing one or more electron-withdrawing groups. Process for the production of ethylene glycol from glycol aldehyde thus prepared.

  乙二醇醛的制备工艺，该工艺包括在由含铑催化剂前体和/或含钴催化剂前体和pKa≥3.5的酸及促进剂XR3组成的催化剂体系存在下，使甲醛与氢气和一氧化碳反应，X代表P、As或Sb，每个R代表一个（不）类似的取代或未取代的烃基；至少一个R代表一个含有一个或多个抽电子基团的芳基。 由由此制备的乙二醇醛生产乙二醇的工艺。
• Production of carboxylic acids from alcohols
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0144935A2

  公开（公告）日：1985-06-19

  A process for the production of organic carboxylic acids by the catalytic reaction of alcohols and carbon monoxide in contact with an organic ester or a compound which under the reaction conditions is convertible to an organic ester, all in contact with a homogeneous catalyst system containing rhodium metal atom and lithium iodide.

  一种通过醇和一氧化碳与有机酯或在反应条件下可转化为有机酯的化合物的催化反应生产有机羧酸的工艺，所有反应均与含有金属铑原子和碘化锂的均相催化剂体系接触。
• Process for producing organic acids
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0144949A2

  公开（公告）日：1985-06-19

  A process for the production of organic carboxylic acids by the catalytic reaction of mixtures of formic acid and organic esters in contact with a homogeneous catalyst system containing rhodium metal atom and lithium iodide.

  一种通过甲酸和有机酯混合物与含有金属铑原子和碘化锂的均相催化剂体系接触进行催化反应生产有机羧酸的工艺。
• Production of carboxylic acids from organic formate esters
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0146823A1

  公开（公告）日：1985-07-03

  A process for the production of organic carboxylic acids by the catalytic reaction of organic formate esters in contact with a homogeneous catalyst system containing rhodium metal atom and lithium iodide.

  一种通过有机甲酸酯与含有金属铑原子和碘化锂的均相催化剂体系接触的催化反应生产有机羧酸的工艺。