2-tert-butylphenoxytetraphenylantimony | 364604-97-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-tert-butylphenoxytetraphenylantimony
• 英文别名: 2-t-Butylphenoxytetraphenylantimony；(2-tert-butylphenoxy)-tetraphenyl-λ5-stibane
• CAS: 364604-97-7
• 化学式: C₃₄H₃₃OSb
• 分子量: 579.385
• InChiKey: OUWIXWQEBONPQQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.89
• 重原子数：
  36
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-叔丁基苯酚 、 pentaphenylantimony 以 甲苯 为溶剂， 以84%的产率得到2-tert-butylphenoxytetraphenylantimony
  参考文献：
  名称：

  摘要：

  2-tert-Butylphenoxytetraphenylantimony Ph4SbOC6H4(Bu-t)-2 was prepared by the reaction of pentaphenyl antimony with 2-tert-butylphenol in toluene at 20 degreesC. The structure of the obtained compound was determined by X-ray diffraction. The Sb atom in this compound has a distorted trigonal-bipyramidal coordination with the aroxy group in the axial position. The Sb-C(Ph)(eq) and Sb-C(Ph)(ax) distances are 2.111(7)-2.138(7) and 2.180(7) Angstrom; the Sb-O and O-C-Ar distances are 2.143(4) and 1.363(8) Angstrom, respectively. The C(Ph)(ax)SbOAr axial angle is 174.1(2)degrees, while the SbOC angle is 126.7(4)degrees.

  DOI：

  10.1023/a:1011337615742