[Cu(2-picolinate)2(H2O)2](malonic acid) | 1133964-85-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(2-picolinate)2(H2O)2](malonic acid)
• CAS: 1133964-85-8
• 化学式: C₃H₄O₄*C₁₂H₁₂CuN₂O₆
• 分子量: 447.845
• InChiKey: ANZMKWUBHRZJAL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-吡啶甲酸 、 丙二酸 、 水 、 copper(II) malonate 以 甲醇 为溶剂， 以58%的产率得到[Cu(2-picolinate)2(H2O)2](malonic acid)
  参考文献：
  名称：

  Segregated self-assembly and pillaring action of aliphatic dicarboxylic acids in the super structure of Cu–picolinate complexes

  摘要：

  Three new supramolecular assemblies of co-crystallized metal complexes and aliphatic dicarboxylic acids, {[Cu(pic)(2)(H2O)(2)](H(2)mal)}(n) (1), {[Cu(pic)(2)(H2O)(2)](H(2)mal)(2)(H2O)(2)}(n) (2) and {[Cu(pic)(2)(MeOH)](H(2)succ)}(n) (3) {Hpic = 2-picolinic acid, H(2)mal = malonic acid and H(2)succ = succinic acid} have been synthesized and characterized by X-ray single-crystal structure determination. The crystal packings of the complexes reveal that supramolecular associations of the monomeric complex units lead to the formation of layers through hydrogen bonding. In all the complexes, the dicarboxylic acid units connect the 2-D layers to act as pillars. The interaction between water molecules and the dicarboxylic acid plays an important role in the overall supramolecular assembly. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.11.061